Home
Class 12
CHEMISTRY
Z' in the following sequence of reaction...

Z' in the following sequence of reactions is
`C_(6)H_(6)overset(HNO_(3)//H_(2)SO_(4))underset(Delta)rarr W overset(Zn//HCl)rarr X overset(NaNO_(2))underset(HCl)rarr Y overset(H_(2)O//H_(3)PO_(2))rarr Z`

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To find the compound Z in the given sequence of reactions, we will analyze each step carefully. ### Step-by-step Solution: 1. **Starting Compound**: The reaction begins with benzene, which is represented by the formula \( C_6H_6 \). 2. **Nitration of Benzene**: The first step involves the nitration of benzene using a mixture of nitric acid (\( HNO_3 \)) and sulfuric acid (\( H_2SO_4 \)). This reaction generates a nitronium ion (\( NO_2^+ \)), which acts as an electrophile. Benzene, being a nucleophile due to its pi electrons, undergoes electrophilic substitution to form nitrobenzene (\( C_6H_5NO_2 \)). - **Product W**: Nitrobenzene (\( C_6H_5NO_2 \)) 3. **Reduction of Nitrobenzene**: The next step involves the reduction of nitrobenzene using zinc and hydrochloric acid (\( Zn/HCl \)). This reaction reduces the nitro group (\( -NO_2 \)) to an amino group (\( -NH_2 \)), resulting in the formation of aniline. - **Product X**: Aniline (\( C_6H_5NH_2 \)) 4. **Diazotization of Aniline**: The aniline is then treated with sodium nitrite (\( NaNO_2 \)) in the presence of hydrochloric acid (\( HCl \)) at low temperatures (0 to 5 degrees Celsius). This process is known as diazotization, where the amino group is converted into a diazonium salt (\( C_6H_5N_2^+Cl^- \)). - **Product Y**: Diazonium salt (\( C_6H_5N_2^+Cl^- \)) 5. **Reduction of Diazonium Salt**: Finally, the diazonium salt is treated with water and phosphorous acid (\( H_3PO_2 \)). This reaction reduces the diazonium group, effectively removing it and regenerating benzene. - **Product Z**: Benzene (\( C_6H_6 \)) ### Final Answer: Thus, the compound Z in the sequence of reactions is **Benzene** (\( C_6H_6 \)). ---

To find the compound Z in the given sequence of reactions, we will analyze each step carefully. ### Step-by-step Solution: 1. **Starting Compound**: The reaction begins with benzene, which is represented by the formula \( C_6H_6 \). 2. **Nitration of Benzene**: The first step involves the nitration of benzene using a mixture of nitric acid (\( HNO_3 \)) and sulfuric acid (\( H_2SO_4 \)). This reaction generates a nitronium ion (\( NO_2^+ \)), which acts as an electrophile. Benzene, being a nucleophile due to its pi electrons, undergoes electrophilic substitution to form nitrobenzene (\( C_6H_5NO_2 \)). - **Product W**: Nitrobenzene (\( C_6H_5NO_2 \)) ...
Promotional Banner

Topper's Solved these Questions

  • AMINES

    DISHA PUBLICATION|Exercise Exercise - 1 : Concept Builder (Topicwise)(TOPIC - 3 : Concept Applicator)|13 Videos
  • ALDEHYDES, KETONES AND CARBOXYLIC ACIDS

    DISHA PUBLICATION|Exercise Exercise - 2 : Concept Applicator|27 Videos
  • BIOMOLECULES

    DISHA PUBLICATION|Exercise Exercise - 2 : Concept Applicator|30 Videos

Similar Questions

Explore conceptually related problems

Z' in the following sequence of reaction is C_6 H_6 overset(HNO_3 // H_2 SO_4) underset(Delta) to W overset(Zn//HCl) to X overset(NaNO_2) underset(HCl, 0-5^@C) to Y overset(H_2 O//H_3 PO_2) to Z

overset(HNO_(3)//H_(2)SO_(4))(rarr) A underset(433 K)overset("NaOH")(rarr)B, B is

Identify Z in the following sequence of reactions - CH_(3)COONH_(4) overset(Delta)rarr X overset(P_(2)O_(5))rarr Y overset(H_(2)O//H)rarr Z

The final product in the following sequence of reaction is C_(6)H_(5)NH_(2) underset(273 - 278 K)overset(NaNO_(2) + HCl)rarr A overset(NaOH)rarr B

C_(6)H_(6)overset(HNO_(3))underset(H_(2)SO_(4))rarr X overset(Cl_(2))underset(FeCl_(3))rarr Y In the above sequence Y can be

In the following sequence of reaction, the end product is : HC-=CHoverset(Hg^(2+)//H_(2)SO_(4))rarr(A) overset(CH_(3)MgX)underset([H_(2)O])rarr(B)overset([O])rarr(C)

Identify the product (E ) in the following sequence of reactions. overset(Br_2)(rarr)Aoverset(Sn//HCl)(rarr)B underset(273-278K)overset(NaNO_2//HCl)(rarr)Coverset(H_2O // H_3PO_2)(rarr) Dunderset(OH^-)overset(KMnO_4)(rarr)E

DISHA PUBLICATION-AMINES-Exercise - 2 : Concept Applicator
  1. Identify product C in the following reaction sequence : CH(3)overset...

    Text Solution

    |

  2. Among the following compounds, the increasing order of their basic str...

    Text Solution

    |

  3. Z' in the following sequence of reactions is C(6)H(6)overset(HNO(3)/...

    Text Solution

    |

  4. The product -(C ) obtained in the following sequence of reactions is

    Text Solution

    |

  5. A compound A has a molecules formula C(7)H(7)NO. On tratement with Br(...

    Text Solution

    |

  6. 3, 5 - Dibromotoluene can be best synthesised by

    Text Solution

    |

  7. Which of the following is the strongest base?

    Text Solution

    |

  8. The relative order of basic character of the following compounds is

    Text Solution

    |

  9. Which of the following can undergo electrophilic substitution when tre...

    Text Solution

    |

  10. When aniline reacts with oil of bitter almonds (C(6)H(5)CHO) condensat...

    Text Solution

    |

  11. Aniline is an activated system for electrophilic substitution The comp...

    Text Solution

    |

  12. The final product C, obtained in this reaction would be

    Text Solution

    |

  13. Aniline in a set of reaction yielded a product D. The strucutre o...

    Text Solution

    |

  14. The major organic product formed from the following reaction :

    Text Solution

    |

  15. Text Solution

    |

  16. C (major product) is -

    Text Solution

    |

  17. (II) overset((i)LiAlH(4))underset((ii)H(2)O)rarr III The basicity or...

    Text Solution

    |

  18. The correct stability order of the following resonance structures is ...

    Text Solution

    |

  19. The correct order of basicities of the following componds is 2. C...

    Text Solution

    |

  20. In the reaction shown below, the major product(s) formed is/are

    Text Solution

    |