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Which of the following can undergo elect...

Which of the following can undergo electrophilic substitution when treated with nitrous acid at `0^(@)C`?

A

`C_(6)H_(5)NH_(2)`

B

`C_(6)H_(5)NHCH_(3)`

C

`C_(6)H_(5)N(CH_(3))_(2)`

D

None

Text Solution

Verified by Experts

The correct Answer is:
C
Nitrosonium ion, `overset(+)NO` from `HONO` is a weak electrophile, hence it can attack only on highly activated beznene nucleus, provided proper position, p - or o - is free.
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DISHA PUBLICATION-AMINES-Exercise - 2 : Concept Applicator
  1. Which of the following is the strongest base?

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  2. The relative order of basic character of the following compounds is

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  3. Which of the following can undergo electrophilic substitution when tre...

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  4. When aniline reacts with oil of bitter almonds (C(6)H(5)CHO) condensat...

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  5. Aniline is an activated system for electrophilic substitution The comp...

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  6. The final product C, obtained in this reaction would be

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  7. Aniline in a set of reaction yielded a product D. The strucutre o...

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  8. The major organic product formed from the following reaction :

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  10. C (major product) is -

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  11. (II) overset((i)LiAlH(4))underset((ii)H(2)O)rarr III The basicity or...

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  12. The correct stability order of the following resonance structures is ...

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  13. The correct order of basicities of the following componds is 2. C...

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  14. In the reaction shown below, the major product(s) formed is/are

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  15. In the following reactions, the major product W is

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  16. In which of the following reaction cyanide will be obtained as a major...

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  17. Choose the appropriate product for this reaction overset("1. "LiAlH...

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  18. Product 'P' in the above reaction is

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  19. The following reaction is

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  20. In this reaction, [X] will be -

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