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Note: In the following questions a state...

Note: In the following questions a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices.
Assertion : `(CH_3)_3 C^(+)` is more stable than `(CH_3)_2 CH^(+)` ion.
Reason : `(CH_3)_3 C^(+)` has trigonal planar structure.

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To solve the question regarding the stability of the carbocations `(CH_3)_3 C^(+)` and `(CH_3)_2 CH^(+)`, we will analyze the assertion and the reason provided. ### Step-by-Step Solution: 1. **Identify the Carbocations**: - The first carbocation is `(CH_3)_3 C^(+)`, which is a tertiary carbocation. - The second carbocation is `(CH_3)_2 CH^(+)`, which is a secondary carbocation. 2. **Determine Stability of Carbocations**: - The stability of carbocations generally increases with the number of alkyl groups attached to the positively charged carbon. This is due to hyperconjugation and the inductive effect of alkyl groups. - Tertiary carbocations are more stable than secondary carbocations because they have more alkyl groups donating electron density to stabilize the positive charge. 3. **Count the Number of Alpha-Hydrogens**: - For `(CH_3)_3 C^(+)`: There are 9 alpha-hydrogens (from the three methyl groups). - For `(CH_3)_2 CH^(+)`: There are 6 alpha-hydrogens (from the two methyl groups and one hydrogen on the secondary carbon). - More alpha-hydrogens contribute to greater stability. 4. **Conclusion on Assertion**: - Since `(CH_3)_3 C^(+)` has more alkyl groups and alpha-hydrogens than `(CH_3)_2 CH^(+)`, the assertion that `(CH_3)_3 C^(+)` is more stable than `(CH_3)_2 CH^(+)` is **true**. 5. **Analyze the Reason**: - The reason states that `(CH_3)_3 C^(+)` has a trigonal planar structure. - While it is true that carbocations are typically trigonal planar due to sp² hybridization, the stability of the carbocation is not solely due to its shape. The stability is primarily influenced by the number of alkyl groups and hyperconjugation. 6. **Conclusion on Reason**: - The reason provided is not a correct explanation for the assertion because it does not address the primary factor affecting stability (the number of alkyl groups). Therefore, the reason is **false**. ### Final Answer: - The assertion is true, and the reason is false. The correct option is **B** (Assertion is true, Reason is false).
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