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During the reaction : CH3 CONH2 overse...

During the reaction :
`CH_3 CONH_2 overset(P_2 O_5)(to) CH_3 CN`
the hybridisation state of carbon changes from

A

`sp^3` to `sp`

B

`sp^3` to `sp^2`

C

`sp^2` to `sp^3`

D

`sp^2` to `sp`

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AI Generated Solution

The correct Answer is:
To determine the change in hybridization state of carbon during the reaction from CH₃CONH₂ to CH₃CN, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactant and Product**: - The reactant is CH₃CONH₂ (Acetamide). - The product is CH₃CN (Acetonitrile). 2. **Analyze the Structure of the Reactant (CH₃CONH₂)**: - The structure of CH₃CONH₂ can be represented as: ``` H H \ / C / \ H C=O | N-H ``` - In this structure, the carbon atom (C) attached to the carbonyl group (C=O) is sp² hybridized because it forms three sigma bonds (one with the carbon in CH₃, one with the oxygen in C=O, and one with the nitrogen in NH₂) and one pi bond (in the C=O double bond). 3. **Analyze the Structure of the Product (CH₃CN)**: - The structure of CH₃CN can be represented as: ``` H H \ / C / \ H C≡N ``` - In this structure, the carbon atom (C) attached to the nitrogen in the CN group is sp hybridized because it forms one sigma bond with the carbon in CH₃ and two pi bonds with the nitrogen in the triple bond (C≡N). 4. **Determine the Change in Hybridization**: - The hybridization of the carbon in CH₃CONH₂ is sp². - The hybridization of the carbon in CH₃CN is sp. - Therefore, the change in hybridization state of carbon during the reaction is from sp² to sp. 5. **Conclusion**: - The hybridization state of carbon changes from sp² in CH₃CONH₂ to sp in CH₃CN. ### Final Answer: The hybridization state of carbon changes from sp² to sp.
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MODERN PUBLICATION-ORGANIC CHEMISTRY: BASIC PRINCIPLES AND TECHNIQUES-(Competition File) MULTIPLE CHOICE QUESTIONS (Organic Compounds)
  1. Which of the following hybridisation has maximum s-characters

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  2. The IUPAC name of the compound: CH3 - underset(underset(O)||)C - CH...

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  3. During the reaction : CH3 CONH2 overset(P2 O5)(to) CH3 CN the hybr...

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  4. Which of the following is not an isomer of but-1-yne ?

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  5. How many sigma and pi bonds are there in the molecule of tetracyanoeth...

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  6. Which of the following series contains nucleophiles only ?

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  7. Which of the following is a one electron species ?

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  8. Which of the following is not an electrophile ?

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  9. Which of the following is an electrophile ?

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  10. Which of the following is an example of elimination reaction?

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  11. In which of the following, all are nucleophiles?

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  12. The reaction represents

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  13. Which of the following reactions represents SN reaction ?

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  14. The IUPAC name of the compound CH(2) = CH - CH(CH(3))(2) is:

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  15. The IUPAC name of CH3-underset(CONH2)underset(|)C=CH-CH2-underset(OH)u...

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  16. The structure of 4-Methylpent-2-en-1-ol is

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  17. Arrangements of (CH(3))(3)C-,(CH(3))(2)CH-,CH(3).CH(2)- when attached ...

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  18. In the compound CH(2)=CH-CH(2)-CH(2)-C-=CH the C(2)-C(3) bond is of

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  19. C6 H5 OH and C2 H5 OH can be distinguished by

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  20. Write IUPAC names of the CH3CH=C(CH3)2 compound.

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