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A metal crystallizes into two cubic phas...

A metal crystallizes into two cubic phases, face-centred cubic and body-centred cubic, which have unit cell lengths `3.5` and `3.0 A`, respectively. Calculate the ratio of densities of fcc and bcc.

Text Solution

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Density of a crystal is
`d = (Z xx "Formula mass of substance")/(N_A xx a^3)`
Now, for bcc, `Z = 4` and for bcc, `Z = 2`
`:. d("fcc") = (Z xx "Formula mass of substance")/(N_A xx (305 A)^3)`
`d("bcc") = (2 xx "Atomic mass of metal")/(N_A xx (3.0 A)^3)`
`:. (d("fcc"))/(d("bcc")) = 4/2 xx ((3.0)^3)/(3.5)^3 = 1.26`.
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