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Why is the extraction of copper from pyr...

Why is the extraction of copper from pyrites more difficult than that from its oxide ore through reduction?

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The group of `Delta_r G^@` vs T in Ellingham diagram for the formation of oxides shows that the copper-copper oxide line is almost at the top. Therefore, it is very easy to reduce oxide ores of copper directly to metal by heating with coke. This is because `Delta G^@` vs T lines for CO has negative slope at higher temperature and therefore, can easily reduce `Cu_2 O` to copper. However, the Gibbs energies of formation of most sulphides are greater than that for `CS_2` . In fact , `CS_2` is an endothermic compound.
Moreover, there is no CS analogous to CO for which `Delta G^@` vs T graphs slope downward. Therefore, extraction of copper from pyrite ore `(Cu_2 S)` is difficult.
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MODERN PUBLICATION-GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS-NCERT FILE (Ncert Textbook Exercises)
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  2. What is the role of depressant in froth floatation process?

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  3. Why is the extraction of copper from pyrites more difficult than that ...

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  9. State the role of silica in the metallurgy of copper.

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  10. What is meant by the term "chromatography"?

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  11. What criterion is followed for the selectrion of the stationary phase ...

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  12. Describe a method for refining nickel.

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  15. How is ‘cast iron’ different from ‘pig iron”?

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  16. Differentiate between “minerals” and “ores”.

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  17. Why copper matte is put in silica lined converter?

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  18. (a) Give an example of zone refining of metals. (b) What is the role ...

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  19. How is leaching carried out in case of low grade copper ores?

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  20. Why is zinc not extracted from zinc oxide through reduction using CO?

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