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Cinnabar (HgS) and galena (PbS) on roast...

Cinnabar `(HgS)` and galena `(PbS)` on roasting often give their respective metals, but zinc blende `(ZnS)` does not. Give reason.

Text Solution

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On roasting sulphides are partly converted to their respective oxides. Since the oxides of lead and mercury are unstable, these bring about the reduction of their respective sulphides to the corresponding metals.
`PbS + 2PbO overset("Heat")to underset("unstable")(3Pb) + SO_2`
`HgS + 2HgO overset("Heat")to underset("unstable")(Hg) + SO_2`
However, zinc oxide is stable and it does not reduce ZnS to Zn.
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