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Why Mn^(2+) compounds are more stable th...

Why `Mn^(2+)` compounds are more stable than `Fe^(2+)` compounds towards oxidation to their + 3 state ?

A

`Mn^(2+)` is more stable with high 3rd ionisation energy

B

`Mn^(2+)` is bigger in size

C

`Mn^+` has completely filled d-orbitals

D

`Mn^(2+)` does not exist

Text Solution

Verified by Experts

The correct Answer is:
A

Electronic configuration of `Mn^(2+)` is `[Ar] 3d^5` . It has stable half filled configuration. Therefore, it has a high 3rd ionisation energy and is stable towards oxidation to their +3 oxidation state.
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MODERN PUBLICATION-D AND F-BLOCK ELEMENTS-COMPETITION FILE (MULTIPLE CHOICE QUESTION ((B) MULTIPLE CHOICE QUESTION FROM COMPETITIVE EXAMINATION))
  1. The bivalent metal ion having maximum paramagnetic behaviour among ...

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  2. When a brown compound of manganese (A) is treated with HCl it gives a ...

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  3. Why Mn^(2+) compounds are more stable than Fe^(2+) compounds towards o...

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  4. The correct basicity order of the following lanthanide ions is -

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  5. When MnO2 is fused with KOH and KNO3 , a coloured compound is forme...

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  6. In the following reaction, ZnO is respectively acting as a/an (i) Zn...

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  7. Identify the cases(s) where there in change in oxidation number.

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  8. Of the following outer electronic configurations of atoms, the highest...

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  9. Which of the following pair is an amphoteric oxide ?

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  10. KMnO(4) acts as on oxidising agent in alkaline medium. When alkaline K...

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  11. Incorrect statement with reference to Ce (Z = 58).

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  12. When a mixture of solid NaCl and solid K(2)Cr(2)O(7) is heated with co...

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  13. Which of the following statement is wrong?

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  14. Maximum oxidation state of uranium and plutonium are respectively :

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  15. What is the shape and magnetic nature of permanganate ion?

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  16. The highest value of the calculated spin-only magnetic moment (in BM)...

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  17. The element that usucally dose NOT show variable oxidation states is ...

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  18. A overset(4KOH.O2)(to) underset("green")(2B ) + 2H2O 3B overset(...

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  19. Which of the following statements about the interstitial compounds is ...

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  20. Thermal decomposition of a Mn compound (X) at 513 K results in compoun...

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