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Consider the reaction: H(2)SO(3)(aq)+S...

Consider the reaction:
`H_(2)SO_(3)(aq)+Sn^(4+)(aq)+H_(2)O(l)toSn^(2+)(aq)+HSO_(4)^(-)(aq)+3H^(+)(aq)`
Which of the following statements is correct?

A

`Sn4^(+)` is the oxidizing agent because it undergoes oxidation.

B

`Sn4^(+)` is the reducing agent because it undergoes oxidation.

C

`H2SO_(3)` is the reducing agent because it undergoes oxidation.

D

`H2SO_(3)` is the reducing agent because it undergoes reduction.

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given redox reaction and determine the correct statement, we will follow these steps: ### Step 1: Identify the oxidation states of the elements in the reactants and products. - In `H₂SO₃`, the oxidation state of sulfur (S) can be calculated as follows: - Let the oxidation state of S be x. - The oxidation state of H is +1 and O is -2. - The equation becomes: \[ 2(+1) + x + 3(-2) = 0 \implies 2 + x - 6 = 0 \implies x = +4 \] - Therefore, the oxidation state of sulfur in `H₂SO₃` is +4. - In `Sn^(4+)`, the oxidation state of Sn is +4. - In `Sn^(2+)`, the oxidation state of Sn is +2. - In `HSO₄^(-)`, the oxidation state of sulfur can be calculated similarly: - Let the oxidation state of S be y. - The equation becomes: \[ +1 + y + 4(-2) = -1 \implies 1 + y - 8 = -1 \implies y = +6 \] - Therefore, the oxidation state of sulfur in `HSO₄^(-)` is +6. ### Step 2: Determine the changes in oxidation states. - In the reaction, `H₂SO₃` (S from +4 to +6 in `HSO₄^(-)`) indicates that sulfur is oxidized (loss of electrons). - `Sn^(4+)` (Sn from +4 to +2 in `Sn^(2+)`) indicates that tin is reduced (gain of electrons). ### Step 3: Identify the oxidizing and reducing agents. - The reducing agent (RA) is the species that gets oxidized. Here, `H₂SO₃` is the reducing agent as it loses electrons. - The oxidizing agent (OA) is the species that gets reduced. Here, `Sn^(4+)` is the oxidizing agent as it gains electrons. ### Step 4: Evaluate the statements provided in the options. - Based on the analysis: - `Sn^(4+)` is the oxidizing agent because it undergoes reduction. - `H₂SO₃` is the reducing agent because it undergoes oxidation. ### Conclusion: The correct statement is that `Sn^(4+)` is the oxidizing agent, and `H₂SO₃` is the reducing agent.

To analyze the given redox reaction and determine the correct statement, we will follow these steps: ### Step 1: Identify the oxidation states of the elements in the reactants and products. - In `H₂SO₃`, the oxidation state of sulfur (S) can be calculated as follows: - Let the oxidation state of S be x. - The oxidation state of H is +1 and O is -2. - The equation becomes: \[ ...
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DISHA PUBLICATION-REDOX REACTIONS-EXERCISE-2 : CONCEPT APPLICATOR
  1. Consider the reaction: H(2)SO(3)(aq)+Sn^(4+)(aq)+H(2)O(l)toSn^(2+)(a...

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  2. In which of the following is the highest oxidation state not possible?

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  3. Oxidation state of nitrogen is incorrectly given for:

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  4. For the reaction M^(x+)+MnO(4)^(ө)rarrMO(3)^(ө)+Mn^(2+)+(1//2)O(2) ...

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  5. Arrange the following in the order of their decreasing electrode poten...

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  6. Equivalent mass of oxidizing agent in the reaction, SO(2)+2H(2)S rar...

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  7. An unknown oxidising agent contains the element Y in + 5 state. If it ...

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  8. For the red ox reaction : Cr2O(7)^(2-) +I^(-) +H^(+) rarr Cr^(3+) + ...

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  9. The oxidation states of the most electronegative element in the produc...

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  10. In which of the following pairs, there is greatest difference in the o...

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  11. The correct decreasing order ofoxidation number ofoxygen in compounds ...

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  12. When KMnO(4) acts as an oxidising agnet and ultimetely from MnO(4)^(2-...

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  13. The oxidation state of iodine in H(4)IO(6)^(-) is:

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  14. The reaction in which hydrogen peroxide acts as a reducting agent is .

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  15. The atomic number of an element is 22. The highest oxidation state exh...

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  16. Consider the following statements Reaction KIO(3) + 5Kl + 6HCl = 3...

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  17. The number of mole of KMnO(4) that will be needed to react completely ...

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  18. Which of the following is not a redox reaction ?

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  19. Which of the following reactions is not a redox reaction?

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  20. Equivalent weight of MnO(4)^(ɵ) in acidic neutral and basic media are ...

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  21. If equal volumes of 1 M KMnO(4) and 1M K(2)Cr(2)O(7) solutions are all...

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