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In reaction of KMnO4 and Mohr's salt, Fe...

In reaction of `KMnO_4` and Mohr's salt, `FeSO_4` is oxidised to

A

`Fe^(2+)`

B

`Fe^(3+)`

C

Fe

D

All of these

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The correct Answer is:
To determine what `FeSO4` is oxidized to when it reacts with `KMnO4`, we can follow these steps: ### Step 1: Identify the Oxidation States In `FeSO4`, iron (Fe) is in the +2 oxidation state (Fe²⁺). In `KMnO4`, manganese (Mn) is in the +7 oxidation state (MnO4²⁻). ### Step 2: Determine the Reaction In a redox reaction, one species is oxidized (loses electrons) and another is reduced (gains electrons). Here, `KMnO4` acts as an oxidizing agent, meaning it will reduce itself while oxidizing another species. ### Step 3: Write the Half-Reaction for Manganese The half-reaction for the reduction of manganese can be written as: \[ \text{MnO}_4^- + 8\text{H}^+ + 5\text{e}^- \rightarrow \text{Mn}^{2+} + 4\text{H}_2\text{O} \] This shows that Mn is reduced from +7 to +2 by gaining 5 electrons. ### Step 4: Write the Half-Reaction for Iron Since `FeSO4` contains Fe²⁺, the oxidation half-reaction can be written as: \[ \text{Fe}^{2+} \rightarrow \text{Fe}^{3+} + \text{e}^- \] This indicates that Fe²⁺ is oxidized to Fe³⁺ by losing one electron. ### Step 5: Balance the Electrons To balance the electrons transferred in the overall reaction, we need to ensure that the number of electrons lost by iron equals the number of electrons gained by manganese. Since 5 electrons are gained by Mn, we need 5 Fe²⁺ ions to provide these electrons: \[ 5\text{Fe}^{2+} \rightarrow 5\text{Fe}^{3+} + 5\text{e}^- \] ### Step 6: Combine the Half-Reactions Now we can combine the half-reactions: \[ \text{MnO}_4^- + 8\text{H}^+ + 5\text{Fe}^{2+} \rightarrow \text{Mn}^{2+} + 4\text{H}_2\text{O} + 5\text{Fe}^{3+} \] ### Conclusion In this reaction, `FeSO4` (Fe²⁺) is oxidized to `Fe³⁺`.

To determine what `FeSO4` is oxidized to when it reacts with `KMnO4`, we can follow these steps: ### Step 1: Identify the Oxidation States In `FeSO4`, iron (Fe) is in the +2 oxidation state (Fe²⁺). In `KMnO4`, manganese (Mn) is in the +7 oxidation state (MnO4²⁻). ### Step 2: Determine the Reaction In a redox reaction, one species is oxidized (loses electrons) and another is reduced (gains electrons). Here, `KMnO4` acts as an oxidizing agent, meaning it will reduce itself while oxidizing another species. ...
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In the reaction of Mohr's salt [FeSO_4(NH_4)_2SO_4.6H_2O] with oxalate ions in the presence of H_2O_2 and H^(o+) ions, [Fe(C_2O_4)_3]^(3-) ion is formed. Calculate the minimum mass of Mohr's salt and K_2C_2O_4 required to prepare 10 g of K_3Fe(C_2O_4)_2 .

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DISHA PUBLICATION-REDOX REACTIONS-EXERCISE-1 : CONCEPT BUILDER ( TOPICWISE )
  1. In the reaction 3Mg + N2 rarr Mg3N2

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  2. One gas bleaches the colour of flowers by reduction, while the other b...

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  3. In reaction of KMnO4 and Mohr's salt, FeSO4 is oxidised to

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  4. Match the columns

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  5. Oxidation number of chromium in potassium dichromate is

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  6. Phosphorus has the oxidation state +3 in

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  7. A compound contains atoms A, B and C. the oxidation number of A is +2,...

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  8. The brown - ring complex compound of iron is formulated as [Fe(H2O)5(N...

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  9. The oxidation number of sulphur in S2F2, H2S respectively, are

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  10. The oxidation number of cobalt in K [Co(CO)(4)] is

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  11. Oxidation number ofnitrogen in (NH4)2SO4 is

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  12. In which of the following compounds iron has lowest oxidation state?

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  13. In which of the compounds does 'maganese' exhibit highest oxidation nu...

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  14. On reduction of KMnO(4) by oxalic acid in acidic medium, the oxidation...

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  15. Among the following, identify the species with an atom in +6 oxidatio...

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  16. The oxidation state of chromium in the final product formed by the rea...

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  17. in which of the following transition metal complexes does the metal ex...

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  18. In which of the following compounds , the oxidation number of iodine i...

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  19. The oxide which cannot act as reducing agent is

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  20. The oxidation number of an element in a compound is evaluated on the b...

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