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For the red ox reaction : Cr2O(7)^(2-)...

For the red ox reaction :
`Cr_2O_(7)^(2-) +I^(-) +H^(+) rarr Cr^(3+) + I_2 + H_2O` the correct coefficients of the reactants for the balanced equation are

A

`{:(Cr_(2)O_(7)^(2-),I^(-),H^(+)),(1,3,14):}`

B

`{:(Cr_(2)O_(7)^(2-),I^(-),H^(+)),(1,6,14):}`

C

`{:(Cr_(2)O_(7)^(2-),I^(-),H^(+)),(2,6,14):}`

D

`{:(Cr_(2)O_(7)^(2-),I^(-),H^(+)),(1,6,7):}`

Text Solution

AI Generated Solution

The correct Answer is:
To balance the redox reaction given by: \[ \text{Cr}_2\text{O}_7^{2-} + \text{I}^- + \text{H}^+ \rightarrow \text{Cr}^{3+} + \text{I}_2 + \text{H}_2\text{O} \] we will follow these steps: ### Step 1: Identify the oxidation states - In \(\text{Cr}_2\text{O}_7^{2-}\), chromium (Cr) has an oxidation state of +6. - In \(\text{I}^-\), iodine (I) has an oxidation state of -1. - In \(\text{Cr}^{3+}\), chromium has an oxidation state of +3. - In \(\text{I}_2\), iodine has an oxidation state of 0. - In \(\text{H}^+\), hydrogen has an oxidation state of +1. - In \(\text{H}_2\text{O}\), oxygen has an oxidation state of -2 and hydrogen is +1. ### Step 2: Write the half-reactions 1. **Reduction half-reaction** (for Cr): \[ \text{Cr}_2\text{O}_7^{2-} + 14 \text{H}^+ + 6 \text{e}^- \rightarrow 2 \text{Cr}^{3+} + 7 \text{H}_2\text{O} \] 2. **Oxidation half-reaction** (for I): \[ 6 \text{I}^- \rightarrow 3 \text{I}_2 + 6 \text{e}^- \] ### Step 3: Combine the half-reactions Now we can combine the half-reactions: \[ \text{Cr}_2\text{O}_7^{2-} + 14 \text{H}^+ + 6 \text{I}^- \rightarrow 2 \text{Cr}^{3+} + 3 \text{I}_2 + 7 \text{H}_2\text{O} \] ### Step 4: Identify the coefficients of the reactants From the balanced equation, we can see the coefficients of the reactants: - Coefficient of \(\text{Cr}_2\text{O}_7^{2-}\) is **1**. - Coefficient of \(\text{I}^-\) is **6**. - Coefficient of \(\text{H}^+\) is **14**. ### Final Answer The correct coefficients of the reactants are: - \(\text{Cr}_2\text{O}_7^{2-}\): 1 - \(\text{I}^-\): 6 - \(\text{H}^+\): 14

To balance the redox reaction given by: \[ \text{Cr}_2\text{O}_7^{2-} + \text{I}^- + \text{H}^+ \rightarrow \text{Cr}^{3+} + \text{I}_2 + \text{H}_2\text{O} \] we will follow these steps: ### Step 1: Identify the oxidation states - In \(\text{Cr}_2\text{O}_7^{2-}\), chromium (Cr) has an oxidation state of +6. ...
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DISHA PUBLICATION-REDOX REACTIONS-EXERCISE-2 : CONCEPT APPLICATOR
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  3. For the red ox reaction : Cr2O(7)^(2-) +I^(-) +H^(+) rarr Cr^(3+) + ...

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  4. The oxidation states of the most electronegative element in the produc...

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  5. In which of the following pairs, there is greatest difference in the o...

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  6. The correct decreasing order ofoxidation number ofoxygen in compounds ...

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  7. When KMnO(4) acts as an oxidising agnet and ultimetely from MnO(4)^(2-...

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  8. The oxidation state of iodine in H(4)IO(6)^(-) is:

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  9. The reaction in which hydrogen peroxide acts as a reducting agent is .

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  10. The atomic number of an element is 22. The highest oxidation state exh...

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  11. Consider the following statements Reaction KIO(3) + 5Kl + 6HCl = 3...

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  12. The number of mole of KMnO(4) that will be needed to react completely ...

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  13. Which of the following is not a redox reaction ?

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  14. Which of the following reactions is not a redox reaction?

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  15. Equivalent weight of MnO(4)^(ɵ) in acidic neutral and basic media are ...

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  16. If equal volumes of 1 M KMnO(4) and 1M K(2)Cr(2)O(7) solutions are all...

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  17. Hydrazine reacts with KIO(3) in presence of HCl as : N(2)H(4)+IO(3)^...

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  18. The equivalent weight of iron in Fe(2)O would be:

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  19. E^(θ) values of some redox couples are given below. On the basis of th...

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  20. A solution contains Fe^(2+), Fe^(3+) and T^(-) ions. This solution was...

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