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In the reaction CH(3) C -= C^(-) - N...

In the reaction
`CH_(3) C -= C^(-) - Na^(+) +(CH_(3))_(2) CH - Cl to ?`
the product formed is .

A

propene

B

propyne

C

propyne and propene

D

4 - methylpentyne - 2

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AI Generated Solution

The correct Answer is:
To solve the reaction given in the question, we need to analyze the reactants and the type of reaction taking place. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are: - An alkynyl anion: `CH3C≡C^(-)Na^(+)` (which is sodium acetylide) - An alkyl halide: `(CH3)2CH-Cl` (which is 2-chloro-2-methylpropane) 2. **Recognize the Reaction Type**: This reaction is a nucleophilic substitution reaction (S_N2 mechanism), where the nucleophile (the alkynyl anion) will attack the carbon atom bonded to the chlorine in the alkyl halide, leading to the formation of a new carbon-carbon bond. 3. **Mechanism of the Reaction**: - The alkynyl anion (`CH3C≡C^(-)`) will attack the carbon atom of the alkyl halide (`(CH3)2CH-Cl`), displacing the chloride ion (Cl^-) and forming a new compound. - The carbon atom in the alkyl halide that is bonded to chlorine is a tertiary carbon, which is favorable for the S_N2 reaction due to steric hindrance. 4. **Product Formation**: - After the nucleophilic attack, the product formed will be `CH3C≡C-CH(CH3)2`, which is 4-methyl-2-pentyne. - The triple bond is located between the second and third carbon atoms in the chain. 5. **Naming the Product**: - The longest carbon chain containing the triple bond has five carbon atoms, making it a pentyne. - The methyl group is on the fourth carbon when numbering from the end closest to the triple bond. - Therefore, the IUPAC name of the product is **4-methyl-2-pentyne**. ### Final Answer: The product formed in the reaction is **4-methyl-2-pentyne**.

To solve the reaction given in the question, we need to analyze the reactants and the type of reaction taking place. ### Step-by-Step Solution: 1. **Identify the Reactants**: The reactants are: - An alkynyl anion: `CH3C≡C^(-)Na^(+)` (which is sodium acetylide) - An alkyl halide: `(CH3)2CH-Cl` (which is 2-chloro-2-methylpropane) ...
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DISHA PUBLICATION-HYDROCARBONS-EXERCISE -1 : CONCEPT BUILDER (TOPIC WISE )
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  2. Which of the following reagent is used for the conversion of 2 - hexy...

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  3. In the reaction CH(3) C -= C^(-) - Na^(+) +(CH(3))(2) CH - Cl to ?...

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  4. Ammoniacal silver nitrate forms a white precipitate easily with:

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  5. When acetylene is passed through dil. H(2)SO(4) in the presence of HgS...

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  6. Identify a reagent from the following list which can easily distinguis...

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  7. The end product of the following sequences of operations is: CaC(2) ...

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  8. Combustion of which of the following compounds ( in the presence of ex...

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  9. Choose the correct alkyne and reagents for the preparation of

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  10. Which of the following has lowest dipole moment?

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  11. Ph-Cequiv C-CH(3)overset(Hg^(2+)//H^(+))toA, A is

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  12. The synthesis of 3-octyne is achieved by adding a bromoalkane into a m...

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  13. Which alkyne will give 3-ethylhexane on catalytic hydrogenation?

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  14. Reduction of 2 - butyne with sodium in liquid ammonia gives predomi...

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  15. Acetylene reacts with HCN in the presence of Ba(CN)(2) to yield :

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  16. A compound (C(5)H(8)) reacts with ammoniacal AgNO(3) to give a white p...

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  17. Which one of the following compounds react with methylamagnesium iodil...

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  18. But- 2-yne contains :

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  19. Nr-(CH(2))(12)-C-=CHoverset(NaNH(2))(to)(A)overset("Lindlar")underset(...

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  20. The product of the reaction between ethyl benzene and N - bromosuccin...

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