Home
Class 12
CHEMISTRY
The effective number of atoms per unit c...

The effective number of atoms per unit cell in a face centred cube and body centred cube are :

A

4,2

B

2,4

C

14,9

D

3,2

Text Solution

AI Generated Solution

The correct Answer is:
To determine the effective number of atoms per unit cell in a face-centered cubic (FCC) and body-centered cubic (BCC) structure, we can follow these steps: ### Step 1: Understanding the Face-Centered Cubic (FCC) Structure In an FCC unit cell: - There are atoms located at each of the 8 corners of the cube. - There is also one atom at the center of each of the 6 faces of the cube. ### Step 2: Calculating Contribution from Corner Atoms in FCC Each corner atom is shared among 8 adjacent unit cells. Therefore, the contribution of one corner atom to the unit cell is: \[ \text{Contribution from corner atoms} = \frac{1}{8} \times 8 = 1 \text{ atom} \] ### Step 3: Calculating Contribution from Face Atoms in FCC Each face atom is shared between 2 unit cells. Therefore, the contribution of one face atom to the unit cell is: \[ \text{Contribution from face atoms} = \frac{1}{2} \times 6 = 3 \text{ atoms} \] ### Step 4: Total Effective Number of Atoms in FCC Adding the contributions from the corner and face atoms: \[ \text{Total atoms in FCC} = 1 + 3 = 4 \text{ atoms} \] ### Step 5: Understanding the Body-Centered Cubic (BCC) Structure In a BCC unit cell: - There are atoms located at each of the 8 corners of the cube. - There is also one atom located at the center of the cube. ### Step 6: Calculating Contribution from Corner Atoms in BCC Similar to FCC, the contribution from the corner atoms is: \[ \text{Contribution from corner atoms} = \frac{1}{8} \times 8 = 1 \text{ atom} \] ### Step 7: Calculating Contribution from Body Center Atom in BCC The body-centered atom is not shared with any other unit cell, so its contribution is: \[ \text{Contribution from body center atom} = 1 \text{ atom} \] ### Step 8: Total Effective Number of Atoms in BCC Adding the contributions from the corner and body center atoms: \[ \text{Total atoms in BCC} = 1 + 1 = 2 \text{ atoms} \] ### Final Answer - The effective number of atoms per unit cell in a Face-Centered Cubic (FCC) structure is **4 atoms**. - The effective number of atoms per unit cell in a Body-Centered Cubic (BCC) structure is **2 atoms**. ### Summary - FCC: 4 atoms - BCC: 2 atoms

To determine the effective number of atoms per unit cell in a face-centered cubic (FCC) and body-centered cubic (BCC) structure, we can follow these steps: ### Step 1: Understanding the Face-Centered Cubic (FCC) Structure In an FCC unit cell: - There are atoms located at each of the 8 corners of the cube. - There is also one atom at the center of each of the 6 faces of the cube. ### Step 2: Calculating Contribution from Corner Atoms in FCC ...
Promotional Banner

Topper's Solved these Questions

  • THE SOLID STATE

    DISHA PUBLICATION|Exercise EXERCISE -2 : CONCEPT APPLICATOR|30 Videos
  • THE SOLID STATE

    DISHA PUBLICATION|Exercise EXERCISE -2 : CONCEPT APPLICATOR|30 Videos
  • THE s-BLOCK ELEMENTS

    DISHA PUBLICATION|Exercise Exercise - 2 : Concept Applicator|30 Videos
  • THERMODYNAMICS

    DISHA PUBLICATION|Exercise Exercise|114 Videos

Similar Questions

Explore conceptually related problems

what is the difference between the number of atoms per unit cell in face - centred cube and body - centred cube ?

The number of atoms per unit cell in a simple cube, face - centred cube and body - centred cube are respectively :

The number of atoms per unit cell ina simple cubic ,face-centred cubic and body-centred cubic are . . .. .. .. Respectively :

What is the number of atoms per unit cell in a body centred cubic structure ?

What would be the effective number of atoms per unit cell in end centred cubic uit cel, if this type of unit cell exist in nautre?

What is the total number of atoms per unit cell in a face centred cubic (fcc) structure ?

DISHA PUBLICATION-THE SOLID STATE-EXERCISE -1 : CONCEPT BUILDER
  1. In the spinel structure, oxides, ions are cubical-closest packed where...

    Text Solution

    |

  2. What would be the effective number of atoms per unit cell in end centr...

    Text Solution

    |

  3. The effective number of atoms per unit cell in a face centred cube and...

    Text Solution

    |

  4. In the closed packing of atoms A ("radius":r(a)), the radius of atom B...

    Text Solution

    |

  5. In a compound ,atoms of element Y from ccp lattice and those of elemen...

    Text Solution

    |

  6. Which of the following is the incorrect statement?

    Text Solution

    |

  7. The range of radius ratio (cationic to anionic) for an octahedral arra...

    Text Solution

    |

  8. Structure of a mixed oxide is cubic closed - packed (ccp) .The cubic u...

    Text Solution

    |

  9. Lattice energy of a solid increases if

    Text Solution

    |

  10. In graphite, electrons are

    Text Solution

    |

  11. A crystalline solid

    Text Solution

    |

  12. Among solid the highest melting point is established by

    Text Solution

    |

  13. The major binding force of diamond, silicon and quartz is

    Text Solution

    |

  14. Which one of the following forms a molecular solid when solidified?

    Text Solution

    |

  15. The total number of elements of symmetry in a cubic crystal is

    Text Solution

    |

  16. Uncharged molecules or atoms are never crystallized in

    Text Solution

    |

  17. Face-centred cubic packing of uniform spherical units is represented b...

    Text Solution

    |

  18. The number of terrahedral and octahedral holes in a hexagonal primitiv...

    Text Solution

    |

  19. AB crystallizes in a body centred cubic lattice with edge length a equ...

    Text Solution

    |

  20. Among the following which has the highest cation to anion size ratio ...

    Text Solution

    |