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Condiser the reactions, (i) (CH(3))(2)...

Condiser the reactions,
(i) `(CH_(3))_(2)CH-CH_(2)Broverset(C_(2)H_(5)OH)rarr(CH_(3))_(2)CH-CH_(2)OC_(2)H_(5)+HBr`
(ii) `(CH_(3))_(2)CH-CH_(2)Broverset(C_(2)H_(5)O^(-))rarr(CH_(3))_(2)CH-CH_(2)OC_(2)H_(5)+Br^(-)`
The mechanism of reactions (i) and (ii) are respectively :

A

`S_N1` and `S_N2`

B

`S_N1` and `S_N1`

C

`S_N2` and `S_N2`

D

`S_N2` and `S_N1`

Text Solution

Verified by Experts

The correct Answer is:
A

A strong nucleophile favours the `S_N2` reaction and a weak nucleophile favours the `S_N1` reaction. First reaction is `S_N1` reaction because `C_2H_5OH` is used as solvent which is a weak nucleophile. Second reaction is `S_N2` reaction because `C_2H_5O^(-)` is Strong nuclcophile.
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