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Allyl phenyl ether can be prepared by he...

Allyl phenyl ether can be prepared by heating:

A

`C_(6)H_(5)Br+CH_(2)=CH-CH_(2)-ON a`

B

`CH_(2)=CH-CH_(2)-Br+C_(6)H_(5)ON a`

C

`C_(6)H_(5)-CH=CH-Br+CH_(3)-ON a`

D

`CH_(2)=CH-Br+C_(6)H_(5)-CH_(2)-ON a`

Text Solution

AI Generated Solution

The correct Answer is:
To prepare allyl phenyl ether, we can use the Williamson synthesis method, which involves the reaction of an alkoxide with a primary halide. Here’s a step-by-step breakdown of how to arrive at the correct answer: ### Step 1: Understand the Structure of Allyl Phenyl Ether Allyl phenyl ether consists of an allyl group (CH2=CH-CH2) bonded to a phenyl group (C6H5) through an oxygen atom. The general structure can be represented as: \[ \text{C6H5-O-CH2-CH=CH2} \] ### Step 2: Identify the Reactants To synthesize allyl phenyl ether, we need: 1. An alkoxide (which can be sodium phenoxide, C6H5O^-Na^+). 2. A primary halide that contains the allyl group (for example, allyl bromide, CH2=CH-CH2Br). ### Step 3: Williamson Synthesis Reaction In the Williamson synthesis, the alkoxide ion attacks the carbon atom of the primary halide, leading to the formation of the ether and the elimination of a halide ion (Br^- in this case). ### Step 4: Analyze the Given Options - **Option A: Aryl bromide (C6H5Br)** - This is not a primary alkyl halide and will not undergo the Williamson synthesis. - **Option B: Allyl bromide (CH2=CH-CH2Br)** - This is a primary halide and can react with sodium phenoxide to form allyl phenyl ether. - **Option C: C6H5CH=CHBr** - This is not a primary halide and will not yield allyl phenyl ether. - **Option D: CH2=CHBr (vinyl bromide)** - This will not yield allyl phenyl ether as it does not contain the correct structure for the desired product. ### Step 5: Conclusion The correct reactants to prepare allyl phenyl ether through heating are found in **Option B** (Allyl bromide with sodium phenoxide). ### Final Answer: Allyl phenyl ether can be prepared by heating allyl bromide (CH2=CH-CH2Br) with sodium phenoxide (C6H5O^-Na^+). ---

To prepare allyl phenyl ether, we can use the Williamson synthesis method, which involves the reaction of an alkoxide with a primary halide. Here’s a step-by-step breakdown of how to arrive at the correct answer: ### Step 1: Understand the Structure of Allyl Phenyl Ether Allyl phenyl ether consists of an allyl group (CH2=CH-CH2) bonded to a phenyl group (C6H5) through an oxygen atom. The general structure can be represented as: \[ \text{C6H5-O-CH2-CH=CH2} \] ### Step 2: Identify the Reactants To synthesize allyl phenyl ether, we need: ...
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Knowledge Check

  • Ethers can be prepared by :

    A
    boiling alkyl halide with dry silver oxide
    B
    boiling alkyl halide with ammoniacal KOH
    C
    heating alkyl halide with potassium alkoxide
    D
    heating an excess of alcohol with alumina under pressure
  • NO_(2) can be prepared by heating :

    A
    `NH_(4)NO_(3)`
    B
    `NaNO_(3)`
    C
    `Pb(NO_(3))_(2)`
    D
    `KNO_(3)`
  • Methyl phenyl ether can be obtained by reacting

    A
    phenolate ions and methyl iodide
    B
    methoxide ion and bromobenzene
    C
    methanol and phenol
    D
    bromobenzene and methyl bromide
  • DISHA PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-Exercise - 2 : Concept Applicator)
    1. Allyl phenyl ether can be prepared by heating:

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    2. , Product (P) is :

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    3. Identify the major product,

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    4. An alcohol of formula C(9)H(12)O reacts with Na(2)Cr(2)O(7) to form a ...

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    5. An optically active alcohol of formula C(9)H(12)O(2) produced the foll...

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    6. Succinic acid overset(Delta)(rarr)(A) underset(Delta)overset(NH(3))(ra...

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    7. The structure of product formed in the reaction given below is:

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    8. Which of the following compound is differentiated by NaHCO(3) as well ...

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    9. Which of the following is most reactive towards aqueous HBr?

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    10. Which of the following alcohols on dehydration with conc. H(2)SO(4) wi...

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    11. Dehydration of alcohol by conc. H(2)SO(4) takes place according to fol...

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    12. Product is

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    13. During the dehydration of alcohols to alkenes by heating with conc. H(...

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    14. B(mix)overset(conc.HI)underset(2) larr (CH(3))(3)C-O-CH(3) overset("an...

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    15. ClCH2CH(2)OH is stronger acid than CH(3)CH(2)OH because of :

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    16. CH(3)-CH=CH(2)overset((i)Hg(OA c)(2)//H(2)O)underset((ii)NaBH(4))rarr ...

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    17. What is product of the following sequence of reactions ? (CH(3))(2)C...

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    18. Identify the nature of product in the following reaction

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    19. Which electrophile is likely to be formed as an intermediate in the fo...

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    20. Phenol is

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    21. What is the structure of the major product when phenol is treated with...

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