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For the following reaction, select the s...

For the following reaction, select the statement that best describes the change.
`RCH_(2)OH+PC C [C_(5)H_(5)NH^(+)ClCrO_(3)^(-)] rarr`

A

The alcohol is oxidised to an acid, and the `Cr(VI)` is reduced.

B

The alcohol is oxidized to an aldehyde, and the `Cr(VI)` is reduced.

C

The alcohol is reduced to an aldehyde, and the `Cr(III)` is oxidized.

D

The alcohol is oxidized to a ketone, and the `Cr(VI)` is reduced.

Text Solution

Verified by Experts

The correct Answer is:
B

`Cr^(6+)rarr Cr^(3+)("PCC oxidises "1^(@)" alcohol to aldehyde")`
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DISHA PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-Exercise - 1 : Concept Builder (Topicwise)(TOPIC 2 : Preparation and Properties of Alcohols)
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  5. Product (B) of the above reaction is :

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  13. Reagent used to convert allyl alcohol to acrolein is :

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  16. Acid catalysed hydration of alkenes except ethene leads to the formati...

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  17. Which of the following reagent will convert glycerol to acrolein ?

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