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Formation of which compound given below ...

Formation of which compound given below from 1- butanol needs an oxidising agent?

A

`CH_(3)CH_(2)CH_(2)CH_(2)Br`

B

`CH_(3)CH_(2)CH_(2)CH=O`

C

`(CH_(3)CH_(2)CH_(2)CH_(2))_(2)O`

D

`CH_(3)-CH_(2)CH=CH_(2)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compound requires an oxidizing agent for its formation from 1-butanol, we need to analyze the possible products and their formation processes. ### Step-by-Step Solution: 1. **Identify 1-butanol**: - 1-butanol is a primary alcohol with the structure CH3-CH2-CH2-CH2OH. It has a hydroxyl (-OH) group attached to the first carbon of a four-carbon chain. 2. **Understand Oxidation**: - Oxidation of alcohols typically involves the loss of hydrogen atoms or the addition of oxygen. For primary alcohols, oxidation can lead to aldehydes or carboxylic acids. 3. **Evaluate the Options**: - **Option A: Butyl Bromide (C4H9Br)**: - This compound is formed by replacing the -OH group with a bromine atom. This reaction does not require oxidation; rather, it requires a halogen source. - **Conclusion**: No oxidizing agent needed. - **Option B: Butanaldehyde (CH3CH2CH2CHO)**: - This is an aldehyde formed by the oxidation of 1-butanol. The process involves the removal of hydrogen atoms from the alcohol, which requires an oxidizing agent. - **Conclusion**: An oxidizing agent is needed. - **Option C: Ether (e.g., CH3CH2CH2OCH2CH3)**: - Ethers can be formed from alcohols through dehydration (removal of water) rather than oxidation. This process requires a dehydrating agent, not an oxidizing agent. - **Conclusion**: No oxidizing agent needed. - **Option D: Alkene (e.g., CH3CH2CH=CH2)**: - The formation of alkenes from alcohols typically involves dehydration (removal of water) rather than oxidation. This can occur through either intramolecular or intermolecular dehydration. - **Conclusion**: No oxidizing agent needed. 4. **Final Conclusion**: - The compound that requires an oxidizing agent for its formation from 1-butanol is **Butanaldehyde (Option B)**.

To determine which compound requires an oxidizing agent for its formation from 1-butanol, we need to analyze the possible products and their formation processes. ### Step-by-Step Solution: 1. **Identify 1-butanol**: - 1-butanol is a primary alcohol with the structure CH3-CH2-CH2-CH2OH. It has a hydroxyl (-OH) group attached to the first carbon of a four-carbon chain. 2. **Understand Oxidation**: ...
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DISHA PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-Exercise - 1 : Concept Builder (Topicwise)(TOPIC 2 : Preparation and Properties of Alcohols)
  1. Iodoform can be obtained on warming NaOH and iodine with :

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  2. Which of the following reactions will yield propan-2-ol ? Select the r...

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  3. Formation of which compound given below from 1- butanol needs an oxidi...

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  4. An industrial method of preparation of methanol is

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  5. CH(3)CH(2)OH+HCl overset(ZnCl(2))rarr CH(3)CH(2)Cl+H(2)O In the abov...

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  6. Which carbocation is involved in the above reaction?

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  7. Rate of dehydration of alcohols follows the order

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  8. Reagent used to convert allyl alcohol to acrolein is :

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  9. HBr reacts fastest with

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  10. The best method to prepare cyclohexene from cyclohexanol is by using

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  11. Acid catalysed hydration of alkenes except ethene leads to the formati...

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  12. Which of the following reagent will convert glycerol to acrolein ?

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  13. Which of the following alcohols is least soluble in water ?

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  14. Which of the following will not give iodoform test?

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  15. Ethyl alcohol can be prepared from grignard reagent by the reaction of...

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  16. Glycerol is more viscous than ethanol due to :

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  17. Ethanol and dimethyl ether from a pair of functional isomers. The boil...

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  18. When glycerol is treated with excess of Hl, the product formed is……………...

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  19. Which of the following compounds can be used as antifreeze in automobi...

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  20. In the following sequence of reaction, the product C is CH(3)-Br ove...

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