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Benzyl alcohol is obtained from benzalde...

Benzyl alcohol is obtained from benzaldehyde by:

A

Perkin's reaction

B

Wurtz reaction

C

Cannizzaro's reaction

D

Claisen's reaction

Text Solution

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The correct Answer is:
To obtain benzyl alcohol from benzaldehyde, we can use the Canizzaro reaction. Here is a step-by-step explanation of the process: ### Step-by-Step Solution: 1. **Identify the Reactant**: - The starting compound is benzaldehyde, which has the structure C6H5CHO. It contains a benzene ring (C6H5) and an aldehyde functional group (CHO). 2. **Understand the Canizzaro Reaction**: - The Canizzaro reaction is a redox reaction that occurs with aldehydes that do not have alpha-hydrogens. In this reaction, one molecule of the aldehyde is oxidized to a carboxylic acid, while another molecule is reduced to an alcohol. 3. **Check for Alpha-Hydrogens**: - Benzaldehyde does not have any alpha-hydrogens because the carbon adjacent to the carbonyl group (C=O) is part of the benzene ring. Therefore, it is suitable for the Canizzaro reaction. 4. **Reaction Conditions**: - The reaction is typically carried out in the presence of a strong base (like sodium hydroxide, NaOH). The base facilitates the reaction by deprotonating the aldehyde. 5. **Disproportionation Reaction**: - During the reaction, one molecule of benzaldehyde is oxidized to benzoic acid (C6H5COOH), while another molecule is reduced to benzyl alcohol (C6H5CH2OH). 6. **Final Products**: - The products of the Canizzaro reaction when benzaldehyde is used are benzyl alcohol and benzoic acid. ### Conclusion: - Therefore, benzyl alcohol is obtained from benzaldehyde by the Canizzaro reaction.

To obtain benzyl alcohol from benzaldehyde, we can use the Canizzaro reaction. Here is a step-by-step explanation of the process: ### Step-by-Step Solution: 1. **Identify the Reactant**: - The starting compound is benzaldehyde, which has the structure C6H5CHO. It contains a benzene ring (C6H5) and an aldehyde functional group (CHO). 2. **Understand the Canizzaro Reaction**: ...
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