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CH(3)underset(CH(3))underset(|)(CH)-CH=C...

`CH_(3)underset(CH_(3))underset(|)(CH)-CH=CH_(2)underset((ii)H_(2)O_(2)//OH)overset((i)B_(2)H_(4))toXunderset(140^(@))overset(H_(2)SO_(4))toY`
What is Y ?

A

`CH_(3)-underset(CH_(3))underset("| ")"CH"-CH_(2)-CH_(2)-O-CH_(2)-CH_(2)-underset(CH_(3))underset("| ")"CH"-CH_(3)`

B

`CH_(3)-underset(CH_(3))underset("| ")"CH"-CH=CH_(2)`

C

`CH_(3)-underset(CH_(3))underset("| ")"CH"-underset(CH_(3))underset("| ")"CH"-O-underset(CH_(3))underset("| ")"CH"-CH_(3)`

D

`CH_(3)-overset(CH_(3))overset("| ")underset(C_(2)H_(5))underset("| ")"C "-O-overset(CH_(3))overset("| ")underset(C_(2)H_(5))underset("| ")"C "-CH_(3)`

Text Solution

Verified by Experts

The correct Answer is:
A
`CH_(3)-underset(CH_(3))underset("| ")"CH"-CH=CH_(2)`
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(A) underset(523K)overset(Al_(2)O_(3))(rarr)(B)underset((i)AgOH)overset((ii)HI)(rarr)(C ) underset(423K)overset(Al_(2)O_(3))(rarr)(B)underset((ii)H_(2)O_(2),OH^(-))overset((i)B_(2)H_(6))(rarr)(A) In the above reactions scheme (A) and (C ) are isomers. (B) has a fomula of C_(5)H_(10) , which can also be obtained from the product of the reactions of CH_(3)CH_(2)MgBrCO . GIve structures of (A),(B) and (C ) . So, underset((A))(CH_(3)-overset(CH_(3))overset(|)(C)H-underset(OH)underset(|)(C)H-CH_(3))underset(523K)overset(Al_(2)O_(3))(rarr)underset((B)C_(5)H_(10))(CH_(3)-overset(CH_(3))overset(|)(C)=CH-CH_(3))underset((ii)AgOH)overset((i)HI)(rarr)underset((C))(CH_(3)-underset(OH)underset(|)overset(CH_(3))overset(|)(C)-CH_(2)CH_(3))underset(423K,(-H_(2)O))overset(Al_(2)O_(3))(rarr)underset((B))(CH_(3)-overset(CH_(3))overset(|)(C)=CHCH_(3))underset((ii)H_(2)O_(2),OH^(-))overset((i)B_(2)H_(6))(rarr) CH_(3)-overset(CH_(3))overset(|)(C)H-underset(OH)underset(|)(C)H-CH_(3)

The correct IUPAC name of the following compound is : CH_(3)CH_(2)-underset( CH_(3))underset(|)(C)H-CH=underset(C_(2)H_(5))underset(|)(C)-overset(C_(2)H_(5))overset(|)(C)H-CH_(2)-CH_(2)-CH_(2)-CH_(3)

Write the main product (s) in each of the following reaction : (i) CH_(3) - underset(CH_(3))underset(|)overset(CH_(3))overset(|)(C)-O-CH_(3)+HIrarr (ii) CH_(3) - CH = CH_(2) underset((ii)3H_(2)O_(2)//OH^(-))overset((i)B_(2)H_(6))rarr (iii) C_(6)H_(5) - OH underset((ii)CO_(2),H^(+))overset((i)aq.NaOH)rarr

DISHA PUBLICATION-ALCOHOLS, PHENOLS AND ETHERS-Exercise - 2 : Concept Applicator)
  1. Which of the following alcohols on dehydration with conc. H(2)SO(4) wi...

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  2. Dehydration of alcohol by conc. H(2)SO(4) takes place according to fol...

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  3. Product is

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  4. During the dehydration of alcohols to alkenes by heating with conc. H(...

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  5. B(mix)overset(conc.HI)underset(2) larr (CH(3))(3)C-O-CH(3) overset("an...

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  6. ClCH2CH(2)OH is stronger acid than CH(3)CH(2)OH because of :

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  7. CH(3)-CH=CH(2)overset((i)Hg(OA c)(2)//H(2)O)underset((ii)NaBH(4))rarr ...

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  8. What is product of the following sequence of reactions ? (CH(3))(2)C...

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  9. Identify the nature of product in the following reaction

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  10. Which electrophile is likely to be formed as an intermediate in the fo...

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  11. Phenol is

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  12. What is the structure of the major product when phenol is treated with...

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  13. The structure of the compound that gives a tribromo derivative on trea...

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  14. "Phenol "overset(NaNO(2)//H(2)SO(4))rarr B overset(H(2)O)rarr C overse...

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  15. The major product P in the following reaction is (CH(3))(3)COH+C(2)H...

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  16. An ether, (A) having molecular formula, C(6)H(14)O, when treated with ...

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  17. HBr reacts with H(2)C=CH-OCH(3) under anhydrous conditions at room tem...

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  18. CH(3)underset(CH(3))underset(|)(CH)-CH=CH(2)underset((ii)H(2)O(2)//OH)...

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  19. The reaction can be classified as:-

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  20. Which one is the most acidic compound?

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