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28 g N2 and 6.0 g of H(2) are heated ov...

28 g N2 and 6.0 g of `H_(2)` are heated over catalyst in a closed one litre flask of 450 °C. The entire equilibrium mixture required 500 mL of 1.0 M `H_(2)SO_(4)` for neutralisation. Calculate the value of Kc in `L^(2) "mol"^(2)` for the given reaction.
`N_(2)(g) + 3H_(2)(g) to 2NH_(3)(g)`

Text Solution

Verified by Experts

The correct Answer is:
0.592

Moles of `N_(2) =28/28=1,` moles of `H_(2)=6/2=3`
Moles of `H_(2)SO_(4)` required `=(500 xx 1)/1000 =0.5`
Moles of `NH_(3)` neutralised by `H_(2)SO_(4)=1.0`
`2NH_(3) + H_(2)SO_(4) to (NH_(4))_(2)SO_(4)`
Hence 1 mole of `NH_(3)` by the reaction between `N_(2)` and `H_(2)`
`{:(N_(2),+,3H_(2), `K_( c) =(1 xx 1)/(0.5 xx (1.5)^(3)) = 0.592 mol^(-2) L^(2)`
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