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Assertion :- On cooling ,ammonia lirqui...

Assertion :- On cooling ,ammonia lirquifies first whereas `CO_(2)` requires more cooling.
Reason :- Critical temperatures of ammonia and carbon dioxide are 405.5 K and 304.10 K respectively.

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Gases possess characteristic critical temperature which depends upon the magnitude of intermolecular forces between the gas particles. Critical temperatures of ammonia and carbon dioxide are 405.5 K and 304.10 K respectively. Which of these gases will liquify first when you start cooling from 500 K to their critical temperature ?

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Critical temperature of ammonia is 405.10K which that of carbon dioxide is 304.10 K. Which will liquify first.

Assertion : NH3 is liquidities more easily than CO_(2) . Reason : Critical temperature of NH3 is more than CO_(2) .