A molecule of a substance has a permanent electric dipole moment of magnitude `10^(-29) `C m. A mole of this substance is polarized at low temperature by appling a strong elecrostatic field of magnitude `10^(6) V m^(-1)`. The direction of the field is suddenly changed by an angle of `60^(@)`. Estimate the heat released by the substance in aligning its dipole along the new direction of the field. For simplicity, assume `100%` polarisation of sample.

Explanation

Here dipole moment of each molecules `=10^(-29)` C
As 1 mole of the substance contains `6 xx 10^(23)` molecules.
total dipole moment of all the molecules `p = 6 xx 10^(23) xx 10^(-29)Cm = 6 xx 10^(-6)` Cm
Initial potential energy, `U_(1) =-pE cos theta =-6 xx 10^(-6) xx 10^(6) cos 0^(@) =-6 J`
Final potential energy (when `theta = 60^(@)`), `U_(f) = -6 xx 10^(-6) xx 10^(6) cos 60^(@) = - 3J`
Change in potential energy `=-3 J -(-6J) = 3J`
So, there is loss in potential energy. This must be the energy released by the substance in the form of heat in aligning its dipoles.