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If at certain temperature, the vapour pr...

If at certain temperature, the vapour pressure of pure water is 25 mm Hg and that of a very dilute aqueous urea solution is 24.5 mm Hg, the molality of the solution is

A

`0.02`

B

`1.2`

C

`1.11`

D

`0.08`

Text Solution

Verified by Experts

The correct Answer is:
C

`(P^(@)-P_(s))/(P^(@))=(w_(B))/(m_(B))xx(m_(A))/(w_(A)), (w_(B))/(w_(B)xx w_(A))xx1000xx(m)/(1000)`
`rArr (P^(@)-P_(s))/(P^(@))=" molality " xx(m)/(1000)`
`(25-24.5)/(25)=m xx(18)/(1000)`
`m=(0.02xx1000)/(18)=1.11`
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