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The relative lowering of vapour pressure...

The relative lowering of vapour pressure of an aqueous solution containing a non-volatile solute, is 0.0125. The molality of the solution is

A

`0.70`

B

`0.50`

C

`0.60`

D

`0.80`

Text Solution

Verified by Experts

The correct Answer is:
A

Relative lowering of vapour pressure of an aqueous solution containing nonvolatile solute is equal to mole fraction of solute.
`therefore (P^(@)-P_(s))/(P^(@))=(n)/(n+N)=0.0125`
`rArr (n+N)/(n)=(1)/(0.0125)rArr (N)/(n)=(1)/(0.0125)-1=(0.9875)/(0.0125)`
`therefore (N)/(n)=(0.9875)/(0.0125)`
Now, molality `=(0.0125xx1000)/(0.9875xx18)=0.70`.
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