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Statement 1 : Lowering of vapour pressur...

Statement 1 : Lowering of vapour pressure is directly proportional to the number of species present in the solution.
Statement 2 : The vapour pressure of 0.1M sugar solution is more than 0.1 M KCl solution.

A

Statement 1 is true, statement 2 is true, statement 2 is a correct explanation for statement 2

B

Statement 1 is true, statement 2 is true , statement 2 is not a correct explanation for statement 2

C

Statement 1 is true, statement 2 is false

D

Statement 1 is false, statement 2 is true

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the given statements, we will break down each statement and evaluate their validity based on the principles of colligative properties. ### Step 1: Evaluate Statement 1 **Statement 1:** Lowering of vapor pressure is directly proportional to the number of species present in the solution. **Explanation:** - Colligative properties, including vapor pressure lowering, depend on the number of solute particles in a solution rather than their identity. - When a non-volatile solute is added to a solvent, the vapor pressure of the solvent decreases. The extent of this decrease is directly related to the number of solute particles in the solution. - Therefore, this statement is **true**. ### Step 2: Evaluate Statement 2 **Statement 2:** The vapor pressure of 0.1 M sugar solution is more than 0.1 M KCl solution. **Explanation:** - Sugar (C₁₂H₂₁O₁₁) is a non-electrolyte and does not dissociate in solution. Therefore, a 0.1 M sugar solution has 0.1 moles of solute particles per liter. - KCl, on the other hand, is an electrolyte and dissociates into two ions (K⁺ and Cl⁻) when dissolved in water. Thus, a 0.1 M KCl solution produces 0.2 moles of solute particles per liter (0.1 M KCl → 0.1 M K⁺ + 0.1 M Cl⁻). - Since the vapor pressure lowering is greater for solutions with more solute particles, the vapor pressure of the KCl solution will be lower than that of the sugar solution. - Therefore, this statement is **true**. ### Conclusion: Both statements are true.

To analyze the given statements, we will break down each statement and evaluate their validity based on the principles of colligative properties. ### Step 1: Evaluate Statement 1 **Statement 1:** Lowering of vapor pressure is directly proportional to the number of species present in the solution. **Explanation:** - Colligative properties, including vapor pressure lowering, depend on the number of solute particles in a solution rather than their identity. - When a non-volatile solute is added to a solvent, the vapor pressure of the solvent decreases. The extent of this decrease is directly related to the number of solute particles in the solution. ...
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