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Which of the following is correct for N...

Which of the following is correct for `N_(2)` triple bond

A

3s

B

1p,2s

C

2p,1s

D

3p

Text Solution

AI Generated Solution

The correct Answer is:
To determine the correct statement regarding the triple bond in nitrogen gas (N₂), we need to analyze the electronic configuration and bonding characteristics of nitrogen atoms. ### Step-by-Step Solution: 1. **Identify the Atomic Number of Nitrogen**: - Nitrogen (N) has an atomic number of 7, which means it has 7 electrons. 2. **Write the Electronic Configuration**: - The electronic configuration of nitrogen is: \[ 1s^2 \, 2s^2 \, 2p^3 \] - This indicates that nitrogen has 2 electrons in the 1s orbital, 2 electrons in the 2s orbital, and 3 electrons in the 2p orbital. 3. **Determine the Ground State Configuration**: - In the ground state, the electrons are arranged as follows: - 1s: 2 electrons (paired) - 2s: 2 electrons (paired) - 2p: 3 electrons (one pair and one unpaired electron in separate orbitals). 4. **Excited State Configuration**: - When nitrogen forms a triple bond, one of the 2s electrons can be promoted to the 2p orbital, resulting in: - 1s: 2 electrons (paired) - 2s: 1 electron (unpaired) - 2p: 4 electrons (two pairs and one unpaired electron). - This allows for the formation of three bonds (one sigma bond and two pi bonds) between two nitrogen atoms. 5. **Bonding in N₂**: - The N₂ molecule consists of a triple bond, which includes: - 1 sigma bond formed by the overlap of 2s and 2p orbitals. - 2 pi bonds formed by the side-to-side overlap of the remaining 2p orbitals. 6. **Conclusion**: - Based on the electronic configuration and bonding characteristics, the correct option regarding the N₂ triple bond is: - **Option 3: It involves 2p and 1s orbitals.**
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