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COCO(3((s))hArrCaO((s))+SO(2(g)) with of...

`COCO_(3((s))hArrCaO_((s))+SO_(2(g))` with of the following expression is correct
or
For the equlibrium `CaCO_(3(s))hArrCaO_((s))+CO_(2(s))` the equlibrium constant is perpesented by the following from

A

`K_(p)=(P_(CaO+P_(CO_(2)))//P_(CaCo_(3)))`

B

`K_(p)=P_(CO_(2))`

C

`K_(p)xx(P_(CaO)xxP_(CO_(2))).P_(CaCO_(3))`

D

`(K_(p)[CaP][CO_(2)])/([CaCO_(3)])`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the equilibrium reaction of calcium carbonate (CaCO₃) dissociating into calcium oxide (CaO) and carbon dioxide (CO₂), we need to analyze the equilibrium expressions for both Kp and Kc. ### Step-by-Step Solution: 1. **Write the Balanced Equation:** The given equilibrium reaction is: \[ \text{CaCO}_3(s) \rightleftharpoons \text{CaO}(s) + \text{CO}_2(g) \] 2. **Identify the Phases of Each Component:** - CaCO₃ is a solid (s). - CaO is also a solid (s). - CO₂ is a gas (g). 3. **Understanding the Equilibrium Constant (Kc):** The equilibrium constant expression Kc is based on the concentrations of the gaseous and aqueous species only. Solids and liquids do not appear in the expression. Therefore, for the reaction: \[ K_c = \frac{[\text{Products}]}{[\text{Reactants}]} \] Since both CaCO₃ and CaO are solids, they will not be included in the Kc expression. Thus: \[ K_c = [\text{CO}_2] \] 4. **Understanding the Equilibrium Constant (Kp):** Kp is based on the partial pressures of the gaseous components. For the same reaction: \[ K_p = \frac{P_{\text{Products}}}{P_{\text{Reactants}}} \] Again, since CaCO₃ and CaO are solids, they do not appear in the Kp expression. Therefore: \[ K_p = P_{\text{CO}_2} \] 5. **Conclusion:** The correct expressions for the equilibrium constants are: - For Kc: \( K_c = [\text{CO}_2] \) - For Kp: \( K_p = P_{\text{CO}_2} \) ### Final Answer: - The correct expression for Kp is the partial pressure of CO₂, and for Kc, it is the concentration of CO₂.

To solve the question regarding the equilibrium reaction of calcium carbonate (CaCO₃) dissociating into calcium oxide (CaO) and carbon dioxide (CO₂), we need to analyze the equilibrium expressions for both Kp and Kc. ### Step-by-Step Solution: 1. **Write the Balanced Equation:** The given equilibrium reaction is: \[ \text{CaCO}_3(s) \rightleftharpoons \text{CaO}(s) + \text{CO}_2(g) ...
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