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The solubility product constant K(sp) of...

The solubility product constant `K_(sp)` of `Mg(OH)_(2)` is `9.0 xx 10^(-12)`. If a solution is 0.010 M with respect to `Mg^(2+)` ion, what is the maximum hydroxide ion concentration which could be present without causing the precipitation of `Mg(OH)_(2)`

A

`1.5 xx 10^(-7) M`

B

`3.0 xx 10^(-7) M`

C

`1.5 xx 10^(-5) M`

D

`3.0 xx 10^(-5) M`

Text Solution

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The correct Answer is:
To solve the problem, we need to determine the maximum concentration of hydroxide ions \([OH^-]\) that can be present in a solution containing \(0.010 \, M\) of \(Mg^{2+}\) without causing the precipitation of \(Mg(OH)_2\). The solubility product constant \(K_{sp}\) for \(Mg(OH)_2\) is given as \(9.0 \times 10^{-12}\). ### Step-by-Step Solution: 1. **Write the Dissolution Equation**: The dissolution of magnesium hydroxide can be represented as: \[ Mg(OH)_2 (s) \rightleftharpoons Mg^{2+} (aq) + 2OH^- (aq) \] 2. **Expression for \(K_{sp}\)**: The solubility product constant \(K_{sp}\) is given by the equation: \[ K_{sp} = [Mg^{2+}][OH^-]^2 \] 3. **Substituting Known Values**: We know that the concentration of \(Mg^{2+}\) is \(0.010 \, M\). Let the concentration of hydroxide ions be \(s\). Thus, we can substitute these values into the \(K_{sp}\) expression: \[ K_{sp} = (0.010)(s)^2 \] 4. **Setting Up the Equation**: We can now set up the equation using the given \(K_{sp}\): \[ 9.0 \times 10^{-12} = (0.010)(s)^2 \] 5. **Solving for \(s^2\)**: Rearranging the equation to solve for \(s^2\): \[ s^2 = \frac{9.0 \times 10^{-12}}{0.010} \] \[ s^2 = 9.0 \times 10^{-10} \] 6. **Calculating \(s\)**: Taking the square root of both sides to find \(s\): \[ s = \sqrt{9.0 \times 10^{-10}} = 3.0 \times 10^{-5} \, M \] 7. **Conclusion**: Therefore, the maximum concentration of hydroxide ions \([OH^-]\) that can be present without causing precipitation of \(Mg(OH)_2\) is: \[ [OH^-] = 3.0 \times 10^{-5} \, M \] ### Final Answer: The maximum hydroxide ion concentration which could be present without causing the precipitation of \(Mg(OH)_2\) is \(3.0 \times 10^{-5} \, M\).

To solve the problem, we need to determine the maximum concentration of hydroxide ions \([OH^-]\) that can be present in a solution containing \(0.010 \, M\) of \(Mg^{2+}\) without causing the precipitation of \(Mg(OH)_2\). The solubility product constant \(K_{sp}\) for \(Mg(OH)_2\) is given as \(9.0 \times 10^{-12}\). ### Step-by-Step Solution: 1. **Write the Dissolution Equation**: The dissolution of magnesium hydroxide can be represented as: \[ Mg(OH)_2 (s) \rightleftharpoons Mg^{2+} (aq) + 2OH^- (aq) ...
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