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The relation between DeltaE and DeltaH i...

The relation between `DeltaE` and `DeltaH` is

A

`DeltaH = DeltaE - PDeltaV`

B

`DeltaH=DeltaE+PDeltaV`

C

`DeltaE=DeltaV+DeltaH`

D

`DeltaE=DeltaH+PDeltaV`

Text Solution

AI Generated Solution

The correct Answer is:
To establish the relationship between \(\Delta E\) (change in internal energy) and \(\Delta H\) (change in enthalpy), we can follow these steps: ### Step-by-Step Solution: 1. **Define the Terms**: - \(\Delta E\) represents the change in internal energy of a system. - \(\Delta H\) represents the change in enthalpy of a system. 2. **Understand the Relationship**: - The relationship between \(\Delta H\) and \(\Delta E\) can be expressed as: \[ \Delta H = \Delta E + P\Delta V \] - Here, \(P\) is the pressure and \(\Delta V\) is the change in volume. 3. **Work Done at Constant Pressure**: - The term \(P\Delta V\) represents the work done by the system when it expands or contracts at constant pressure. 4. **Rearranging the Equation**: - From the equation \(\Delta H = \Delta E + P\Delta V\), we can see that if we know the change in internal energy and the work done (in terms of pressure and volume change), we can calculate the change in enthalpy. 5. **Conclusion**: - Therefore, the relationship can be summarized as: \[ \Delta H = \Delta E + P\Delta V \] - This equation shows how the change in enthalpy is related to the change in internal energy and the work done during expansion or contraction.

To establish the relationship between \(\Delta E\) (change in internal energy) and \(\Delta H\) (change in enthalpy), we can follow these steps: ### Step-by-Step Solution: 1. **Define the Terms**: - \(\Delta E\) represents the change in internal energy of a system. - \(\Delta H\) represents the change in enthalpy of a system. ...
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