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The maximum work obtainable from a rever...

The maximum work obtainable from a reversible process is given as

A

`-DeltaA`

B

`DeltaA`

C

`-DeltaG`

D

`DeltaG`

Text Solution

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The correct Answer is:
To determine the maximum work obtainable from a reversible process, we can use the relationship involving Gibbs free energy (ΔG). Here’s a step-by-step solution: ### Step 1: Understand the Gibbs Free Energy Equation The Gibbs free energy change (ΔG) for a process is given by the equation: \[ \Delta G = \Delta H - T \Delta S \] where: - ΔG = change in Gibbs free energy - ΔH = change in enthalpy - T = absolute temperature (in Kelvin) - ΔS = change in entropy ### Step 2: Identify Conditions for Maximum Work In a reversible process, the maximum work (W_max) obtainable is related to the change in Gibbs free energy. For a process to do maximum work, the Gibbs free energy change must be greater than zero: \[ \Delta G > 0 \] ### Step 3: Relate ΔG to Work The maximum work obtainable from a reversible process can be expressed as: \[ W_{max} = -\Delta G \] This means that the maximum work is equal to the negative change in Gibbs free energy. ### Step 4: Conclusion Therefore, the maximum work obtainable from a reversible process is given by: \[ W_{max} = -\Delta G \] This indicates that for a reversible process to yield maximum work, the change in Gibbs free energy must be positive.
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