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The standard heats of formation in Kcal ...

The standard heats of formation in Kcal `mol^(-1)` of `NO_(2)(g)` and `N_(2)O_(4)(g)` are 8.0 and 2.0 respectively. The heat of dimerization of `NO_(2)` in Kcal is. Given : `2NO_(2)(g)hArr N_(2)O_(4)(g)`

A

10

B

`- 6.0`

C

`- 12.0`

D

`- 14.0`

Text Solution

Verified by Experts

The correct Answer is:
D

`DeltaH_("reaction")=DeltaH_(f)^(@)(N_(2)O_(4))-2DeltaH_(f)^(@)(NO_(2))`
`=2-2(8)=-14 kcal`.
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