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Reason for geometrical isomerism shown b...

Reason for geometrical isomerism shown by 2- butene is

A

Chiral carbon

B

Free rotation about single bond

C

Free rotation about double bond

D

Restricted rotation about double bond

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The correct Answer is:
### Step-by-Step Solution: 1. **Understanding Geometrical Isomerism**: Geometrical isomerism (also known as cis-trans isomerism) occurs in compounds that have restricted rotation around a bond, typically a double bond. This restriction leads to different spatial arrangements of groups attached to the carbon atoms involved in the double bond. 2. **Identifying the Compound**: In this case, we are looking at 2-butene, which has the molecular formula C4H8. It consists of a double bond between the second and third carbon atoms. 3. **Drawing the Structure of 2-Butene**: The structure of 2-butene can be represented as: - CH3-CH=CH-CH3 Here, the double bond is between the second and third carbon atoms. 4. **Analyzing the Substituents**: For geometrical isomerism to occur, each carbon involved in the double bond must have different substituents. In 2-butene: - The second carbon (C2) has one hydrogen atom and one methyl group (CH3). - The third carbon (C3) has one hydrogen atom and one methyl group (CH3). 5. **Identifying the Isomers**: - **Cis-2-butene**: Both methyl groups (CH3) are on the same side of the double bond. - **Trans-2-butene**: The methyl groups (CH3) are on opposite sides of the double bond. 6. **Conclusion**: The reason for geometrical isomerism in 2-butene is due to the restricted rotation around the double bond (C=C). This restriction prevents the free rotation that would allow the molecule to convert between different arrangements, leading to distinct isomers. ### Final Answer: The reason for geometrical isomerism shown by 2-butene is the restricted rotation about the double bond (C=C).

### Step-by-Step Solution: 1. **Understanding Geometrical Isomerism**: Geometrical isomerism (also known as cis-trans isomerism) occurs in compounds that have restricted rotation around a bond, typically a double bond. This restriction leads to different spatial arrangements of groups attached to the carbon atoms involved in the double bond. 2. **Identifying the Compound**: In this case, we are looking at 2-butene, which has the molecular formula C4H8. It consists of a double bond between the second and third carbon atoms. 3. **Drawing the Structure of 2-Butene**: The structure of 2-butene can be represented as: - CH3-CH=CH-CH3 ...
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