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Among the three conformations of ethane,...

Among the three conformations of ethane, the order of stability follows the sequence

A

Eclipsed `gt` gauche `gt` staggered

B

Eclipsed `gt` staggered `gt` gauche

C

Staggered `gt` gauche `gt` eclipsed

D

Gauche `gt` staggered `gt` eclipsed

Text Solution

AI Generated Solution

The correct Answer is:
To determine the order of stability among the three conformations of ethane, we need to analyze the different conformations: staggered, eclipsed, and gauche. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Conformations Ethane (C2H6) can adopt three main conformations when viewed along the C-C bond: 1. **Staggered Conformation**: The hydrogen atoms on adjacent carbons are positioned as far apart as possible. 2. **Eclipsed Conformation**: The hydrogen atoms on adjacent carbons are aligned with each other, leading to maximum repulsion. 3. **Gauche Conformation**: This is a specific type of staggered conformation where the two larger groups (in this case, hydrogen atoms) are adjacent to each other, but still staggered. ### Step 2: Analyze Stability - **Staggered Conformation**: This is the most stable conformation because the hydrogen atoms are as far apart as possible, minimizing steric hindrance and torsional strain. - **Gauche Conformation**: This conformation is less stable than staggered but more stable than eclipsed. The hydrogen atoms are still staggered, but they are closer together, leading to some steric strain. - **Eclipsed Conformation**: This is the least stable conformation due to the maximum steric hindrance and torsional strain, as the hydrogen atoms are aligned with each other. ### Step 3: Order of Stability Based on the analysis: 1. **Staggered** (most stable) 2. **Gauche** 3. **Eclipsed** (least stable) Thus, the order of stability of the conformations of ethane is: **Staggered > Gauche > Eclipsed** ### Final Answer The correct sequence of stability among the three conformations of ethane is: **Staggered > Gauche > Eclipsed**. ---

To determine the order of stability among the three conformations of ethane, we need to analyze the different conformations: staggered, eclipsed, and gauche. Here’s a step-by-step breakdown of the solution: ### Step 1: Identify the Conformations Ethane (C2H6) can adopt three main conformations when viewed along the C-C bond: 1. **Staggered Conformation**: The hydrogen atoms on adjacent carbons are positioned as far apart as possible. 2. **Eclipsed Conformation**: The hydrogen atoms on adjacent carbons are aligned with each other, leading to maximum repulsion. 3. **Gauche Conformation**: This is a specific type of staggered conformation where the two larger groups (in this case, hydrogen atoms) are adjacent to each other, but still staggered. ...
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