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Which types of isomerism is shown by 2,3...

Which types of isomerism is shown by 2,3-dichlorobutane

A

Distereo

B

Optical

C

Geometric

D

Structural

Text Solution

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The correct Answer is:
To determine the types of isomerism shown by 2,3-dichlorobutane, we can follow these steps: ### Step 1: Identify the Structure 2,3-dichlorobutane has the following structure: - It is a four-carbon chain (butane) with chlorine atoms attached to the second and third carbon atoms. ### Step 2: Determine Chiral Centers - In 2,3-dichlorobutane, both the second and third carbon atoms are chiral centers because they each have four different groups attached to them: - C2: CH3, H, Cl, and the rest of the carbon chain. - C3: CH3, H, Cl, and the rest of the carbon chain. ### Step 3: Identify Types of Isomerism - The presence of chiral centers indicates that 2,3-dichlorobutane can exhibit **optical isomerism**. This is because chiral compounds can exist as non-superimposable mirror images (enantiomers). ### Step 4: Count the Isomers - For a compound with two chiral centers, the maximum number of stereoisomers can be calculated using the formula \(2^n\), where \(n\) is the number of chiral centers. Here, \(n = 2\), so: \[ 2^2 = 4 \text{ stereoisomers} \] - However, one of these stereoisomers is a meso compound, which is optically inactive because it has a plane of symmetry. Therefore, the actual number of distinct stereoisomers is 3: - 1 meso compound (optically inactive) - 2 enantiomers (optically active) ### Conclusion - 2,3-dichlorobutane exhibits **optical isomerism**. There are a total of **3 stereoisomers**: 1 meso compound and 2 enantiomers.

To determine the types of isomerism shown by 2,3-dichlorobutane, we can follow these steps: ### Step 1: Identify the Structure 2,3-dichlorobutane has the following structure: - It is a four-carbon chain (butane) with chlorine atoms attached to the second and third carbon atoms. ### Step 2: Determine Chiral Centers - In 2,3-dichlorobutane, both the second and third carbon atoms are chiral centers because they each have four different groups attached to them: ...
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