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The formation of cyanohydrin from a keto...

The formation of cyanohydrin from a ketone is an example of

A

Electrophilic addition

B

Nucleophilic addition

C

Nucleophilic substitution

D

Electrophilic substitution

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The correct Answer is:
To determine the type of reaction that the formation of cyanohydrin from a ketone represents, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - We start with a ketone, which has the general structure R-C(=O)-R', where R and R' are hydrocarbon groups. 2. **Nucleophilic Attack**: - The reaction involves the addition of hydrogen cyanide (HCN) to the ketone. In this reaction, the cyanide ion (CN⁻) acts as a nucleophile. - The carbon atom of the carbonyl group (C=O) in the ketone has a partial positive charge due to the electronegativity difference between carbon and oxygen. This makes it susceptible to attack by the nucleophile (CN⁻). 3. **Formation of the Intermediate**: - The nucleophile (CN⁻) attacks the electrophilic carbon of the carbonyl group, leading to the formation of a tetrahedral intermediate. This intermediate has the structure R-C(OH)(CN)-R'. 4. **Protonation**: - The tetrahedral intermediate can then be protonated by an acid (like H₃O⁺), resulting in the formation of the final product, which is a cyanohydrin. The structure of the cyanohydrin is R-C(OH)(CN)-R'. 5. **Conclusion**: - The overall process involves the addition of a nucleophile (CN⁻) to the electrophilic carbon of the ketone, which is characteristic of a nucleophilic addition reaction. ### Final Answer: The formation of cyanohydrin from a ketone is an example of **nucleophilic addition**. ---

To determine the type of reaction that the formation of cyanohydrin from a ketone represents, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - We start with a ketone, which has the general structure R-C(=O)-R', where R and R' are hydrocarbon groups. 2. **Nucleophilic Attack**: ...
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ERRORLESS -GENERAL ORGANIC CHEMISTRY-JEE Section (Only one choice correct answer)
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  2. Amongst the following the most basic compound is :

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  3. The formation of cyanohydrin from a ketone is an example of

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  4. The enolic form of acetone contains

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  5. The C-C bond length of the following molecules is in the order

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  6. Which one of the following behaves both as a nucleophile and an electr...

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  7. Number of pi electrons in cyclobutadienyl anion (C(4)H(4))^(-2) is

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  8. Isomers which can be interconverted through rotation around a single b...

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  9. Homolytic fission of C-C bond in ethane gives an intermediate in which...

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  10. The maximum number of stereoisomers possible for 2-hydroxy-2-methyl bu...

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  11. IUPAC name of {:(CH(3)-CH-CHO),(" |"),(" ...

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  12. Which is the decreasing order of stability (i) CH(3)-overset(+)(CH)-...

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  13. Which has zero dipole moment

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  14. The IUPAC name of succinic acid is

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  15. What is the decreasing order of reactivity amongst the following comp...

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  16. The following compound can exhibits

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  17. निम्न में से कौन-सी स्पिशीज सर्वाधिक स्थायी है?

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  18. The correct statement about the compounds A and B is

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  19. How many optically active stereoisomers are possible for butane-2, 3-d...

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  20. The optically active tartaric acid is named as D-(+)-tartaric acid bec...

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