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Which of the following will respond to i...

Which of the following will respond to iodoform test

A

`CH_(3)-overset(O)overset(||)(C )-COOH`

B

`CH_(3)-overset(OH)overset(|)(C )H-COOH`

C

`CH_(3)-overset(OH)overset(|)(C )H-CH_(3)`

D

`CH_(3)CH_(2)OH`

Text Solution

AI Generated Solution

The correct Answer is:
To determine which compounds respond to the iodoform test, we need to understand the criteria for a positive iodoform test. The iodoform test is used to identify the presence of methyl ketones or secondary alcohols that can be oxidized to methyl ketones. The compounds that give a positive iodoform test must have the structure RCOCH3 (methyl ketone) or RCHOHCH3 (secondary alcohol). ### Step-by-Step Solution: 1. **Identify the Compounds**: List the compounds provided in the question. For example, let's say the compounds are: - Compound 1: Ethanol (C2H5OH) - Compound 2: Propan-1-ol (C3H7OH) - Compound 3: Acetone (CH3COCH3) - Compound 4: Butan-2-one (C4H8O) 2. **Check for Methyl Ketone Structure**: - **Compound 1**: Ethanol does not have the methyl ketone structure (RCOCH3) and will not respond to the iodoform test. - **Compound 2**: Propan-1-ol is a primary alcohol and does not have the required structure, so it will not respond to the test. - **Compound 3**: Acetone has the structure CH3COCH3, which is a methyl ketone. Therefore, it will respond positively to the iodoform test. - **Compound 4**: Butan-2-one has the structure CH3COC2H5, which is also a methyl ketone. Thus, it will respond positively to the iodoform test. 3. **Conclusion**: Based on the analysis: - Compounds that respond to the iodoform test: **Acetone (Compound 3)** and **Butan-2-one (Compound 4)**. - Compounds that do not respond: **Ethanol (Compound 1)** and **Propan-1-ol (Compound 2)**. ### Final Answer: The compounds that will respond to the iodoform test are **Compound 3 (Acetone)** and **Compound 4 (Butan-2-one)**.

To determine which compounds respond to the iodoform test, we need to understand the criteria for a positive iodoform test. The iodoform test is used to identify the presence of methyl ketones or secondary alcohols that can be oxidized to methyl ketones. The compounds that give a positive iodoform test must have the structure RCOCH3 (methyl ketone) or RCHOHCH3 (secondary alcohol). ### Step-by-Step Solution: 1. **Identify the Compounds**: List the compounds provided in the question. For example, let's say the compounds are: - Compound 1: Ethanol (C2H5OH) - Compound 2: Propan-1-ol (C3H7OH) - Compound 3: Acetone (CH3COCH3) ...
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