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Red precipitae is obtained when ethanol ...

Red precipitae is obtained when ethanol solution of dimethylglyoxime is added to ammoniacal `Ni (II)`. Which of the following statement is not true?

A

Red complex has a square planar geometry

B

Complex has symmetrical H-bonding

C

Red complex has a tretrahedral geometry

D

Dimethylglyoxime functions as bidentate ligand.

Text Solution

Verified by Experts

The correct Answer is:
C

`Ni^(2+)+2DMG overset(NH_(4)^(+)OH^(-))(rarr) underset("Red")([Ni(DMG)_(2)])`

DMG is strong field ligand `:.` all `e^(-)` are rearranged as

Hence complex is square planar .
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