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Identify the correct order of solubility...

Identify the correct order of solubility of `Na_(2)S,CuS` and ZnS in aqueous solution

A

CuSgtZnSgt`Na_(2)S`

B

`ZnS gt Na_(2)S gt CuS`

C

`Na_(2)S gt CuS gt ZnS`

D

`Na_(2)S gt ZnS gt CuS`

Text Solution

Verified by Experts

The correct Answer is:
D

Sodium salts are highly soluble. `Cu^(2+)` belongs to the `II^(nd)` group in salt analysis and is precipitated as `CuS`, whereas `Zn^(2+)` belongs to the IV group and is precipitated as ZnS
after CuS because of higher `K_(SP)` of `ZnS`.
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