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Which of the following sequence of react...

Which of the following sequence of reactions (reagent ) can be used for the conversion of `C_6H_5CH_2CH_3` into `C_6H_5CH=CH_3`

A

`SOCl_2 , H_2O`

B

`SO_2Cl_2 , alc.KOH`

C

`Cl_2//hv , H_2O`

D

`SOCl_2` , alc. KOH

Text Solution

AI Generated Solution

The correct Answer is:
To convert `C6H5CH2CH3` (ethylbenzene) into `C6H5CH=CH3` (styrene), we can follow these steps: ### Step 1: Chlorination First, we need to introduce a chlorine atom into the molecule. This can be done by reacting ethylbenzene with thionyl chloride (SOCl2) under high temperature. The reaction will convert the `CH2` group into a `CHCl` group. **Reaction:** \[ C6H5CH2CH3 + SOCl2 \rightarrow C6H5CHClCH3 + HCl + SO2 \] ### Step 2: Elimination Reaction Next, we will perform an elimination reaction to remove the chlorine and a hydrogen atom from the adjacent carbon. This can be achieved through an E2 elimination mechanism. We will use a strong base, such as sodium ethoxide (NaOEt), to facilitate this elimination. **Reaction:** \[ C6H5CHClCH3 + NaOEt \rightarrow C6H5CH=CH3 + NaCl + EtOH \] ### Final Product After the elimination reaction, we obtain the desired product, `C6H5CH=CH3` (styrene). ### Summary of Reagents Used: 1. Thionyl chloride (SOCl2) at high temperature. 2. Sodium ethoxide (NaOEt) for the elimination step. ### Final Answer The correct sequence of reactions to convert `C6H5CH2CH3` into `C6H5CH=CH3` is: 1. `C6H5CH2CH3 + SOCl2 (high temperature) → C6H5CHClCH3` 2. `C6H5CHClCH3 + NaOEt → C6H5CH=CH3`

To convert `C6H5CH2CH3` (ethylbenzene) into `C6H5CH=CH3` (styrene), we can follow these steps: ### Step 1: Chlorination First, we need to introduce a chlorine atom into the molecule. This can be done by reacting ethylbenzene with thionyl chloride (SOCl2) under high temperature. The reaction will convert the `CH2` group into a `CHCl` group. **Reaction:** \[ C6H5CH2CH3 + SOCl2 \rightarrow C6H5CHClCH3 + HCl + SO2 \] ...
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