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2-chlorobutane is heated with alcoholic ...

2-chlorobutane is heated with alcoholic NaOH, the product formed in larger amount is

A

1-butene

B

1-butyne

C

2-butene

D

All of these

Text Solution

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The correct Answer is:
To solve the problem of what product is formed in larger amounts when 2-chlorobutane is heated with alcoholic NaOH, we can follow these steps: ### Step 1: Identify the structure of 2-chlorobutane 2-chlorobutane is a four-carbon alkane with a chlorine atom attached to the second carbon. The structural formula can be represented as: \[ \text{CH}_3 - \text{CH}(\text{Cl}) - \text{CH}_2 - \text{CH}_3 \] ### Step 2: Understand the reaction with alcoholic NaOH When 2-chlorobutane is heated with alcoholic NaOH, a dehydrohalogenation reaction occurs. In this reaction, the alcoholic NaOH will help to eliminate the chlorine atom (Cl) and a hydrogen atom (H) from adjacent carbon atoms, leading to the formation of a double bond. ### Step 3: Elimination of Cl and H The chlorine atom on the second carbon will be eliminated along with a hydrogen atom from the adjacent carbon (the third carbon). This results in the formation of a double bond between the second and third carbon atoms. ### Step 4: Formation of the product After the elimination, the structure of the product will be: \[ \text{CH}_3 - \text{CH} = \text{CH} - \text{CH}_3 \] This compound is known as 2-butene. ### Step 5: Determine the major product Since 2-butene can exist in two isomeric forms (cis and trans), the trans form is generally more stable and will be the major product formed in larger amounts. ### Conclusion The product formed in larger amounts when 2-chlorobutane is heated with alcoholic NaOH is **2-butene**.

To solve the problem of what product is formed in larger amounts when 2-chlorobutane is heated with alcoholic NaOH, we can follow these steps: ### Step 1: Identify the structure of 2-chlorobutane 2-chlorobutane is a four-carbon alkane with a chlorine atom attached to the second carbon. The structural formula can be represented as: \[ \text{CH}_3 - \text{CH}(\text{Cl}) - \text{CH}_2 - \text{CH}_3 \] ### Step 2: Understand the reaction with alcoholic NaOH When 2-chlorobutane is heated with alcoholic NaOH, a dehydrohalogenation reaction occurs. In this reaction, the alcoholic NaOH will help to eliminate the chlorine atom (Cl) and a hydrogen atom (H) from adjacent carbon atoms, leading to the formation of a double bond. ...
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