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Ethylene is converted to X on passing th...

Ethylene is converted to X on passing through a mixture of acidified aqueous solution of palladium chloride and cupric chloride. Which of the following reagents readily takes part addition reaction with X

A

`Br_2`

B

HBr

C

HCl

D

HCN

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to follow these steps: ### Step 1: Identify the starting compound The starting compound is ethylene (C2H4), which has a double bond between the two carbon atoms. ### Step 2: Understand the reaction conditions Ethylene is passed through a mixture of acidified aqueous solutions of palladium chloride (PdCl2) and cupric chloride (CuCl2). This process is known as the Wacker process. ### Step 3: Determine the product (X) In the Wacker process, ethylene is oxidized to form an aldehyde. The reaction can be represented as follows: \[ \text{C}_2\text{H}_4 + \text{Pd}^{2+} + \text{Cu}^{2+} \rightarrow \text{CH}_3\text{CHO} \] Thus, the product X is acetaldehyde (CH3CHO). ### Step 4: Identify the reagents for addition reactions Next, we need to determine which of the provided reagents can readily participate in an addition reaction with the aldehyde (X = CH3CHO). The reagents given are Br2, HBr, HCl, and CN. ### Step 5: Analyze the reactivity of the reagents - **Br2**: Typically reacts with alkenes and alkynes but not directly with aldehydes in a straightforward manner. - **HBr**: Can react with aldehydes, but it is not the strongest nucleophile. - **HCl**: Similar to HBr, it can react with aldehydes. - **CN (Cyanide ion)**: This is a strong nucleophile and will readily react with the carbonyl group in aldehydes. ### Step 6: Determine the strongest nucleophile Among the reagents, CN (from HCN) is the strongest nucleophile. When it reacts with the carbonyl group of the aldehyde, it will form a cyanohydrin. ### Conclusion The reagent that readily takes part in an addition reaction with X (acetaldehyde) is **CN** (from HCN). ### Final Answer The correct answer is CN (Cyanide ion). ---
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