Home
Class 12
CHEMISTRY
Ammonical cuprous chloride will give red...

Ammonical cuprous chloride will give red precipitate with which one of the following

A

`CH_3-C-=C-CH_3`

B

`CH_3-CH=CH_2`

C

`CH_3-C-=CH`

D

`CH_3-CH=CH-CH_3`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding which compound will give a red precipitate with ammonical cuprous chloride, we can follow these steps: ### Step 1: Understand the Reactants Ammonical cuprous chloride (Cu2Cl2 in the presence of NH4OH) is a reagent used to test for the presence of terminal alkynes. Terminal alkynes have a hydrogen atom attached to the carbon-carbon triple bond, making them reactive with this reagent. ### Step 2: Identify the Types of Alkynes There are two types of alkynes: - **Terminal Alkynes**: These have the triple bond at the end of the carbon chain (e.g., ethyne or propyne). - **Non-terminal Alkynes**: These have the triple bond located within the carbon chain (e.g., butyne). ### Step 3: Reaction with Ammonical Cuprous Chloride When terminal alkynes react with ammonical cuprous chloride, they form a complex that results in the formation of a red precipitate. This is due to the formation of cuprous acetylide, which is red in color. ### Step 4: Conclusion Since the question asks for the compound that will give a red precipitate with ammonical cuprous chloride, the answer is **terminal alkynes**. ### Final Answer Ammonical cuprous chloride will give a red precipitate with terminal alkynes. ---
Promotional Banner

Similar Questions

Explore conceptually related problems

Cuprous chloride can be prepared:

Cuprous chloride can be prepared:

Fehling solution gives red precipitate with :

With ammonical cuprous chloride solution, a reddish brown precipitate is obtained on treating with

Explain the following facts: (a). Copper hydroxide is soluble in ammonium hydroxide but not in sodium hydeoxide. (b). Addition of an alkali to cuprous chloride solution gives a yellow precipitate which gradually changes to a red colour.

Assertion: Stannous chloride is a powerful oxidising agent which oxidises mercuric chloride to mercury Reason: Stannous chloride gives grey precipitate with mercuric chloride, but stannic chloride does not do so.