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An equimolar mixture of toluene and chlo...

An equimolar mixture of toluene and chlorobenzene is treated with a mixture of conc. `H_(2)SO_(4)` and conc. `HNO_(3)` Indicate the correct statement from the following :

A

p-nitrotoluene is formed in excess

B

Equimolar amounts of p-nitrotoluene and p-nitrochlorobenzene are formed

C

p-nitrochlorobenzene is formed in excess

D

m-nitrochlorobenzene is formed in excess

Text Solution

Verified by Experts

The correct Answer is:
A

`CH_3`-group is an activating group while chloro group is a deactivating group towards electrophilic substitution reaction. Thus p-nitrotoluene is formed in excess
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ERRORLESS -HYDROCARBON-ORDINARY THINKING (Objective question) (AROMATIC HYDROCARBON)
  1. The product formed when toluene is heated in light with Cl2 and in a...

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  2. Friedel-Crafts reaction using MeCI and anhydrous AICI(3) will take pla...

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  3. An equimolar mixture of toluene and chlorobenzene is treated with a mi...

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  4. Reaction of benzene with Me3COCl in the presence of anhydrous AlCl3 gi...

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  5. Which of the following is aromatic ?

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  6. Complete the following reaction

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  7. Find the major product in the following reaction

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  8. Which of the following group activates the benzene ring most towards e...

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  9. Benzene reacts with I2 in presence of which of the following to give i...

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  10. The final product formed in the reaction is

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  11. The compound with molecular formula C(8)H(10) which will give only two...

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  12. Which compound is aromatic

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  13. Benzene can react with

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  14. Chorination of benzene is not possible in the following reaction :

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  15. Xylenes on oxidation with acidic KMnO4 gives

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  16. Aromatic compounds burn with a sooty flame because

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  17. For preparing monoalkyl benzene, acylation process is preferred than d...

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  18. Which of the following is not formed by the ozonolysis of (o-xylene)

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  19. Point out the wrong statement in relation to the structure of benzene

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  20. Six carbon atoms of benzene are of:

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