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A stainless steel chamber contains Ar ga...

A stainless steel chamber contains Ar gas at a temperature T and pressure P. The total number of Ar atoms in the chamber is n. Now Ar gas in the chamber is rep,aced by `CO_(2)` gas and the total number of `CO_(2)` molecules in the chamber is `n//2` at the same temperature T. The pressure in the chamber now is P'. Which one of the following relations relations holds true ? (Both the gases behave as ideal gases)

A

P'=P

B

P'=2P

C

`P'=P//2`

D

`P' P//4`

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The correct Answer is:
To solve the problem, we will use the ideal gas law, which states that: \[ PV = nRT \] Where: - \( P \) = pressure of the gas - \( V \) = volume of the gas - \( n \) = number of moles of the gas - \( R \) = universal gas constant - \( T \) = temperature of the gas ### Step-by-Step Solution: 1. **Initial Conditions with Argon Gas:** - Let the initial number of moles of Argon gas be \( n \). - The initial pressure of Argon gas is \( P \). - The ideal gas equation can be written as: \[ P \cdot V = n \cdot R \cdot T \tag{1} \] 2. **Final Conditions with Carbon Dioxide Gas:** - When Argon gas is replaced by Carbon Dioxide (CO₂), the number of CO₂ molecules in the chamber is \( \frac{n}{2} \). - We need to find the new pressure \( P' \) when the number of moles of CO₂ is \( \frac{n}{2} \). - The ideal gas equation for CO₂ can be written as: \[ P' \cdot V = \left(\frac{n}{2}\right) \cdot R \cdot T \tag{2} \] 3. **Relating the Two Conditions:** - From equation (1), we can express \( P \): \[ P = \frac{nRT}{V} \tag{3} \] - From equation (2), we can express \( P' \): \[ P' = \frac{\left(\frac{n}{2}\right)RT}{V} = \frac{nRT}{2V} \tag{4} \] 4. **Finding the Relation Between \( P \) and \( P' \):** - Now, we can substitute equation (3) into equation (4): \[ P' = \frac{1}{2} \cdot P \tag{5} \] 5. **Conclusion:** - Thus, the relation that holds true is: \[ P' = \frac{P}{2} \] ### Final Answer: The correct relation is \( P' = \frac{P}{2} \).

To solve the problem, we will use the ideal gas law, which states that: \[ PV = nRT \] Where: - \( P \) = pressure of the gas - \( V \) = volume of the gas - \( n \) = number of moles of the gas ...
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