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Give reasons for the following: (i) Tr...

Give reasons for the following:
(i) Transition elements and their compounds act as catalysts
(ii) `E^(@)` value for `(Mn^(2+) | Mn)` is negative whereas for `(Cu^(2+) | Cu)` is positive.
(iii) Actinoids show irregularities in their electronic configuration.

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