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Ligand(s) with lone pair of elecftron(s)...

Ligand(s) with lone pair of elecftron(s) with vacant orbital to receive back the electrons donated to the metal is/are

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The pi acid ligands donate their lone pairs to the metal to form a normal o bond with the latter in addition to it the vacant orbitals accepct electrons from the filled mental orbitals to form a type of pi bonand which suppliments the o bond Which of the following has lowest M-C bond lenght? [Ni(CO)_(4)] (b) [Mn(CO)_(6)]^(o+) (c) [Fe(CO)_(4)]^(2-) (d) [Co(CO)_(4)]^(Θ) .