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31.2g of ammonium carbamate (NH(2)COONH...

31.2g of ammonium carbamate `(NH_(2)COONH_(4))` was heated in a flask of 5.0L to a temperature of `77^(@)C` .The flask initial contained 1.70g of `NH_(3)` . `NH_(2)COONH_(4)` dissociated to the extent of 50% when equilibrium reaches. Calculate `K_(p)` (in terms of `10^(-2)atm^(3)` for dissociation of `NH_(2)COONH_(4)`

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