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If lambda(1)= and lambda(2) are the wave...

If `lambda_(1)= and lambda_(2)` are the wavelengths of the first members of Lyman and Paschen series respectively, then ` lambda_(1): lambda_(2)`, is

A

`1:3`

B

`1:30`

C

`7:50`

D

`7:108`

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The correct Answer is:
To find the ratio of the wavelengths of the first members of the Lyman and Paschen series, we will use Rydberg's formula for hydrogen spectral lines. ### Step-by-Step Solution: **Step 1: Identify the first members of the Lyman and Paschen series.** - The first member of the Lyman series corresponds to the transition from n=2 to n=1. - The first member of the Paschen series corresponds to the transition from n=4 to n=3. **Step 2: Write Rydberg's formula.** - Rydberg's formula is given by: \[ \frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where \( R \) is the Rydberg constant, \( n_1 \) is the lower energy level, and \( n_2 \) is the higher energy level. **Step 3: Calculate \( \lambda_1 \) for the Lyman series.** - For the Lyman series, \( n_1 = 1 \) and \( n_2 = 2 \): \[ \frac{1}{\lambda_1} = R \left( \frac{1}{1^2} - \frac{1}{2^2} \right) = R \left( 1 - \frac{1}{4} \right) = R \left( \frac{3}{4} \right) \] - Therefore, \[ \lambda_1 = \frac{4}{3R} \] **Step 4: Calculate \( \lambda_2 \) for the Paschen series.** - For the Paschen series, \( n_1 = 3 \) and \( n_2 = 4 \): \[ \frac{1}{\lambda_2} = R \left( \frac{1}{3^2} - \frac{1}{4^2} \right) = R \left( \frac{1}{9} - \frac{1}{16} \right) \] - To combine these fractions, find a common denominator (144): \[ \frac{1}{\lambda_2} = R \left( \frac{16 - 9}{144} \right) = R \left( \frac{7}{144} \right) \] - Therefore, \[ \lambda_2 = \frac{144}{7R} \] **Step 5: Find the ratio \( \frac{\lambda_1}{\lambda_2} \).** - Now, we can find the ratio: \[ \frac{\lambda_1}{\lambda_2} = \frac{\frac{4}{3R}}{\frac{144}{7R}} = \frac{4}{3R} \cdot \frac{7R}{144} = \frac{4 \cdot 7}{3 \cdot 144} \] - Simplifying this gives: \[ \frac{28}{432} = \frac{7}{108} \] **Final Answer:** - The ratio \( \lambda_1 : \lambda_2 = 7 : 108 \).
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RESNICK AND HALLIDAY-HYDROGEN ATOM-PRACTICE QUESTIONS (Single Correct Choice Type)
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