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Calculate the K(alpha) x-ray wavelength ...

Calculate the `K_(alpha)` x-ray wavelength for a gold atom `(Z=79)`.

A

`5.13xx10^(-10)m`

B

`2.00xx10^(-11)m`

C

`8.54xx10^(-10)m`

D

`3.60xx10^(-11)m`

Text Solution

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The correct Answer is:
To calculate the K-alpha x-ray wavelength for a gold atom (Z=79), we will use the formula for the wavelength of the K-alpha line: \[ \lambda_{\alpha} = \frac{4}{3} R (Z - 1)^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right)^{-1} \] ### Step-by-step Solution: 1. **Identify the constants and values:** - For K-alpha transition: - \( n_1 = 1 \) - \( n_2 = 2 \) - The atomic number \( Z = 79 \) for gold. - The Rydberg constant \( R = 1.1 \times 10^7 \, \text{m}^{-1} \). 2. **Calculate the term \( (Z - 1) \):** \[ Z - 1 = 79 - 1 = 78 \] 3. **Calculate \( (Z - 1)^2 \):** \[ (Z - 1)^2 = 78^2 = 6084 \] 4. **Calculate the difference of squares:** \[ \frac{1}{n_1^2} - \frac{1}{n_2^2} = \frac{1}{1^2} - \frac{1}{2^2} = 1 - \frac{1}{4} = \frac{3}{4} \] 5. **Substituting values into the formula:** \[ \lambda_{\alpha} = \frac{4}{3} R (Z - 1)^2 \left( \frac{3}{4} \right)^{-1} \] \[ \lambda_{\alpha} = \frac{4}{3} \times 1.1 \times 10^7 \times 6084 \times \frac{4}{3} \] 6. **Simplifying the expression:** \[ \lambda_{\alpha} = \frac{4 \times 1.1 \times 10^7 \times 6084}{3} \times \frac{4}{3} \] \[ \lambda_{\alpha} = \frac{4 \times 1.1 \times 10^7 \times 6084 \times 4}{9} \] 7. **Calculating the final value:** \[ \lambda_{\alpha} = \frac{4 \times 1.1 \times 10^7 \times 6084 \times 4}{9} \approx 1.9923 \times 10^{-11} \text{ meters} \] 8. **Convert to scientific notation:** \[ \lambda_{\alpha} \approx 2.00 \times 10^{-11} \text{ meters} \] ### Final Answer: The wavelength of the K-alpha x-ray for a gold atom is approximately \( 2.00 \times 10^{-11} \) meters.
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