Home
Class 12
CHEMISTRY
0.70 g of an organic compund when dissol...

0.70 g of an organic compund when dissolved in 32g of acetone produces in an elevation in boiling point of `0.25^(@)C`. Calculate the molecular mass of the organic compound. `(K_(b)" for acetone "=1.72 K kg mol^(-1))`.

Text Solution

Verified by Experts

`M_(B) = (k_(b) xx 1000xx w_(B))/(w_(A) xx Delta T_(b))`
`w_(B) = 4.2 g , w_(A) = 50 g, Delta T_(b) = 1.8 K`
`k_(f) = 1.71 K m^(-1)`
`M_(B) = (1.71 xx 1000 xx 4.2)/(50 xx 1.8)`
`=79.8 g mol^(-1)`
Promotional Banner

Topper's Solved these Questions

  • SOLUTIONS

    MODERN PUBLICATION|Exercise HIGHER ORDER THINKING SKILLS|14 Videos
  • SOLUTIONS

    MODERN PUBLICATION|Exercise COMPETITION FILE (A. MULTIPLE CHOICE QUESTIONS(MCQ))|26 Videos
  • SOLUTIONS

    MODERN PUBLICATION|Exercise REVISION EXERCISES (LONG ANSWER QUESTIONS)|21 Videos
  • SOLID STATE

    MODERN PUBLICATION|Exercise UNIT PRACTICE TEST|13 Videos
  • SURFACE CHEMISTRY

    MODERN PUBLICATION|Exercise COMPETITION FILE (OBJECTIVE TYPE QUESTIONS) (MATCHING LIST TYPE QUESTIONS)|2 Videos

Similar Questions

Explore conceptually related problems

The boiling point of pure acetone is 56.38^(@)C . When 0.707 g of a compound is dissolved in 10 g of acetone there is elevation to 56.88^(@)C in b.p What is the mol.wt. of the comound ? (K_(b)" of acetone"=1.72 K kg mole^(-1))

The boiling a point of benzene is 353.23K. When 1.80 g of a non-volatile solute was dissolved in 90 g of benzene, the boiling point is raised to 354.11 K. Calculate the molar mass of the solute. K_(b) for benzene is 2.53 K kg mol^(-1) .

By dissolving 13.6 g of a substance in 20 g of water, the freezing point decreased by 3.7^(@)C . Calculate the molecular mass of the substance. (Molal depression constant for water = 1.863K kg mol^(-1))

A solution of 0.643 g of an organic compound in 50 mL of benzene (density 0.879 g//mL ) lowered its freezing point from 5.51^(@)C to 5.03^(@)C . Calculate the molecular weight of solid. (K_(f) for benzene is 5.12 K mol^(-1) kg )

MODERN PUBLICATION-SOLUTIONS-REVISION EXERCISES (NUMERICAL PROBLEMS)
  1. Depression in freezing point of 0.1 molal solution of HF is -0.201^(@)...

    Text Solution

    |

  2. 100 mg of a protein was disoved in just enough water to make 10 mL of ...

    Text Solution

    |

  3. What mass of ethylene glycol (molar mass = "62.0 g mol"^(-1)) must be ...

    Text Solution

    |

  4. 15.0 g of an unknown molecular material was dissolved in 450 g of wate...

    Text Solution

    |

  5. What mass of NaCI ("molar mass" =58.5g mol^(-1)) be dissolved in 65g o...

    Text Solution

    |

  6. 6 g of a substance is dissolved in 100 g of water depresses the freezi...

    Text Solution

    |

  7. 5.85 g of NaCl are dissolved in 90 g of water. The mole fraction of Na...

    Text Solution

    |

  8. Calculate the boiling point of a 1M aqueous solution (density 1.04 g M...

    Text Solution

    |

  9. Calculate the osmotic pressure of 0.5% solution of glucose (molecular ...

    Text Solution

    |

  10. Calculate the molar mass of a substance 1 g of which when dissolved i...

    Text Solution

    |

  11. 0.70 g of an organic compund when dissolved in 32g of acetone produces...

    Text Solution

    |

  12. Calculate the freezing point depression and boiling point elevation of...

    Text Solution

    |

  13. The vapour pressure of pure benzene at a certain temperature is 640 mm...

    Text Solution

    |

  14. 18 g of glucose (C(6)H(12)O(6)) is dissolved in 1 kg of water in a sau...

    Text Solution

    |

  15. The freezing point depression of 0.1 molal solution of acetic acid in ...

    Text Solution

    |

  16. (a) Define the following terms : (i) Mole fraction (ii) Ideal solu...

    Text Solution

    |

  17. 1.0 g of non-electrolyte solute dissolved in 50.0 g of benzene lowered...

    Text Solution

    |